Chemical Physics Letters, volume 300, issue 3-4, pages 493-498

Transformation of OH-adduct of 1-chloro-4-iodobutane into intra-molecular radical cation in neutral aqueous solution

Publication type: Journal Article
Publication date: 1999-02-01
scimago Q2
wos Q1
SJR: 0.502
CiteScore: 5.7
Impact factor: 2.8
ISSN: 00092614, 18734448
Physical and Theoretical Chemistry
General Physics and Astronomy
Abstract
The iodine centered OH-adduct formed on reaction of ⋅ OH radicals with 1-chloro-4-iodobutane in neutral aqueous solution transforms (k=5.4×105 s−1) to an intra-molecular radical cation ( Download : Download full-size image ). The unfavorable structural conformation of solute radical cation generated on reaction of ⋅ OH radicals with 1-chloro-5-iodopentane does not allow the transformation of OH-adduct into an intra-molecular radical and instead a dimer radical cation ( Download : Download full-size image ) is formed.
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