Inorganica Chimica Acta, volume 13, pages 141-144
Spectral properties of some 4-substituted pyridine n-oxide complexes with iron perchlorate
Yonezo Maeda
1
,
Yoichiro Sasaki
1
,
YOSHIMASA TAKASHIMA
1
Publication type: Journal Article
Publication date: 1975-01-01
Journal:
Inorganica Chimica Acta
scimago Q2
wos Q2
SJR: 0.386
CiteScore: 6.0
Impact factor: 2.7
ISSN: 00201693, 18733255
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Visible, infrared and Mossbauer spectra of 4-substituted pyridine N-oxide complexes of the formula [Fe(4-ZC 5 H 4 NO) 6 ](ClO 4 ) 2 , where Z = OCH 3 , CH 3 , H, Cl and NO 2 are reported. Spectral data indicate that the six coordinated complexes are of high-spin octahedral structure distorted from O h symmetry. From infrared spectral measurements metal-oxygen stretching vibrations are found to be correlated with the σ pyNO values of the ligand. Crystal field parameters are evaluated from diffuse reflectance spectra and the trend of parameter was discussed in terms of spectrochemical series.
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