On the nature of the spin ground state of iron(II) in Fe(2,9-di-CH3-phenanthroline)2(NCS)2
Publication type: Journal Article
Publication date: 1979-01-01
scimago Q3
wos Q2
SJR: 0.393
CiteScore: 5.5
Impact factor: 3.2
ISSN: 00201693, 18733255
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The temperature dependence of the zero field Mossbauer spectrum and magnetic susceptibility of Fe(2,9-di-CH3-phenanthroline)2(NCS)2 over the range 1.8 to 300 K shows that the complex contains spin quintet iron(II) at all temperatures. The ligand is apparently to the weak field side of the ‘crossover point’ and contrary to the results of a previous study there is no evidence of a transition to a lower multiplicity (triplet or singlet) ground state. The observed decrease of the magnetic moment (4.81 μβ at 302 K to 3.48 μβ at 1.82 K) is consistent with zero field splitting (|D|≈ 5 cm−1) of the ground spin manifold.
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13
Total citations:
13
Citations from 2024:
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(7.69%)
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Dockum B. W., Reiff W. M. On the nature of the spin ground state of iron(II) in Fe(2,9-di-CH3-phenanthroline)2(NCS)2 // Inorganica Chimica Acta. 1979. Vol. 35. pp. 285-287.
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Dockum B. W., Reiff W. M. On the nature of the spin ground state of iron(II) in Fe(2,9-di-CH3-phenanthroline)2(NCS)2 // Inorganica Chimica Acta. 1979. Vol. 35. pp. 285-287.
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TY - JOUR
DO - 10.1016/s0020-1693(00)93452-2
UR - https://doi.org/10.1016/s0020-1693(00)93452-2
TI - On the nature of the spin ground state of iron(II) in Fe(2,9-di-CH3-phenanthroline)2(NCS)2
T2 - Inorganica Chimica Acta
AU - Dockum, Bruce W.
AU - Reiff, William Michael
PY - 1979
DA - 1979/01/01
PB - Elsevier
SP - 285-287
VL - 35
SN - 0020-1693
SN - 1873-3255
ER -
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BibTex (up to 50 authors)
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@article{1979_Dockum,
author = {Bruce W. Dockum and William Michael Reiff},
title = {On the nature of the spin ground state of iron(II) in Fe(2,9-di-CH3-phenanthroline)2(NCS)2},
journal = {Inorganica Chimica Acta},
year = {1979},
volume = {35},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016/s0020-1693(00)93452-2},
pages = {285--287},
doi = {10.1016/s0020-1693(00)93452-2}
}