Oxidations in the H2 O2 /VV/AcOH system. Evidence of vanadium(V) complexes with superoxide anion and singlet dioxygen molecule as ligands
Publication type: Journal Article
Publication date: 1998-07-01
scimago Q3
wos Q2
SJR: 0.393
CiteScore: 5.5
Impact factor: 3.2
ISSN: 00201693, 18733255
Materials Chemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Anthracene, its alkyl derivatives, and alkenes have been found to undergo oxidation by the VvH2O2AcOH catalytic system via a polar mechanism involving the transfer of singlet dioxygen from H2O2 to the unsaturated substrate molecule. The vanadium (V) complex with a singlet dioxygen molecule as ligand was suggested to be the only oxidant species active in the reaction. The Vv(O2•−) complex radical was detected as the only paramagnetic species in the system. Unusual acceleration of the styrene oxidation caused by the 2,6-di-tert-butyl-4-methylphenol additive (BHT) was observed and attributed to lowering the concentration of the Vv(O2•−) complex radical, which is assumed to be an active reductant toward the Vv complex with singlet dioxygen.
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Gekhman A. E. et al. Oxidations in the H2O2/VV/AcOH system. Evidence of vanadium(V) complexes with superoxide anion and singlet dioxygen molecule as ligands // Inorganica Chimica Acta. 1998. Vol. 275-276. pp. 453-461.
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Gekhman A. E., Stolarov I., Moiseeva N. I., Rubaijlo V. L., Vargaftik M., Moiseev I. I. Oxidations in the H2O2/VV/AcOH system. Evidence of vanadium(V) complexes with superoxide anion and singlet dioxygen molecule as ligands // Inorganica Chimica Acta. 1998. Vol. 275-276. pp. 453-461.
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TY - JOUR
DO - 10.1016/s0020-1693(98)00129-7
UR - https://linkinghub.elsevier.com/retrieve/pii/S0020169398001297
TI - Oxidations in the H2O2/VV/AcOH system. Evidence of vanadium(V) complexes with superoxide anion and singlet dioxygen molecule as ligands
T2 - Inorganica Chimica Acta
AU - Gekhman, Alexander E.
AU - Stolarov, Igor
AU - Moiseeva, Natalia I
AU - Rubaijlo, Valentin L
AU - Vargaftik, Michael
AU - Moiseev, I. I.
PY - 1998
DA - 1998/07/01
PB - Elsevier
SP - 453-461
VL - 275-276
SN - 0020-1693
SN - 1873-3255
ER -
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@article{1998_Gekhman,
author = {Alexander E. Gekhman and Igor Stolarov and Natalia I Moiseeva and Valentin L Rubaijlo and Michael Vargaftik and I. I. Moiseev},
title = {Oxidations in the H2O2/VV/AcOH system. Evidence of vanadium(V) complexes with superoxide anion and singlet dioxygen molecule as ligands},
journal = {Inorganica Chimica Acta},
year = {1998},
volume = {275-276},
publisher = {Elsevier},
month = {jul},
url = {https://linkinghub.elsevier.com/retrieve/pii/S0020169398001297},
pages = {453--461},
doi = {10.1016/s0020-1693(98)00129-7}
}