,
volume 101
,
issue 3
,
pages 329-340
Comparative study of carbon monoxide adsorption and oxidation of the chemisorbed species at smooth and platinized platinum electrodes
1
General Electric Corporate Research and Development, Schenectady, NY U.S.A. 02
|
Publication type: Journal Article
Publication date: 1979-08-01
SJR: —
CiteScore: —
Impact factor: —
ISSN: 00220728
General Chemistry
General Medicine
Abstract
The adsorption of carbon monoxide and the anodic oxidation of the chemisorbed species were investigated at room temperature under the same experimental conditions on foils of smooth and platinized platinum for which hydrogen adsorption is very similar. Both the weakly and strongly bonded species (type II and type I species) were formed to the same extent on the two electrodes in acidic electrolytes. While the freshly platinized platinum electrode behaved like the smooth electrode with predominance of the one-site adsorption of CO, the aging of the platinized electrode led to an increase of the two-site adsorption. The oxidation rate of strongly bonded species at constant potential decreased when the extent of two-site adsorption increased. The electrochemical results are discussed in the light of recent work in the gas phase.
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47
Total citations:
47
Citations from 2024:
1
(2.13%)
The most citing journal
Citations in journal:
24
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GOST
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Breiter M. W. Comparative study of carbon monoxide adsorption and oxidation of the chemisorbed species at smooth and platinized platinum electrodes // Journal of Electroanalytical Chemistry and Interfacial Electrochemistry. 1979. Vol. 101. No. 3. pp. 329-340.
GOST all authors (up to 50)
Copy
Breiter M. W. Comparative study of carbon monoxide adsorption and oxidation of the chemisorbed species at smooth and platinized platinum electrodes // Journal of Electroanalytical Chemistry and Interfacial Electrochemistry. 1979. Vol. 101. No. 3. pp. 329-340.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/s0022-0728(79)80044-3
UR - https://doi.org/10.1016/s0022-0728(79)80044-3
TI - Comparative study of carbon monoxide adsorption and oxidation of the chemisorbed species at smooth and platinized platinum electrodes
T2 - Journal of Electroanalytical Chemistry and Interfacial Electrochemistry
AU - Breiter, M. W.
PY - 1979
DA - 1979/08/01
PB - Elsevier
SP - 329-340
IS - 3
VL - 101
SN - 0022-0728
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1979_Breiter,
author = {M. W. Breiter},
title = {Comparative study of carbon monoxide adsorption and oxidation of the chemisorbed species at smooth and platinized platinum electrodes},
journal = {Journal of Electroanalytical Chemistry and Interfacial Electrochemistry},
year = {1979},
volume = {101},
publisher = {Elsevier},
month = {aug},
url = {https://doi.org/10.1016/s0022-0728(79)80044-3},
number = {3},
pages = {329--340},
doi = {10.1016/s0022-0728(79)80044-3}
}
Cite this
MLA
Copy
Breiter, M. W.. “Comparative study of carbon monoxide adsorption and oxidation of the chemisorbed species at smooth and platinized platinum electrodes.” Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, vol. 101, no. 3, Aug. 1979, pp. 329-340. https://doi.org/10.1016/s0022-0728(79)80044-3.