Catalytic reduction of cyclohexanecarbonyl chloride with electrogenerated nickel(I) salen in acetonitrile
Publication type: Journal Article
Publication date: 1998-01-01
scimago Q1
wos Q1
SJR: 0.760
CiteScore: 8.1
Impact factor: 4.1
ISSN: 15726657, 18732569
General Chemical Engineering
Analytical Chemistry
Electrochemistry
Abstract
In the presence of electrogenerated nickel(I) salen in acetonitrile containing tetramethylammonium tetrafluoroborate, cyclohexanecarbonyl chloride is catalytically reduced to form ultimately a tetrameric species, 1,2-dicyclohexylethene-1,2-diol dicyclohexanoate. Initially, the acyl chloride accepts an electron from nickel(I) salen to form an acyl radical, and two acyl radicals couple to afford 1,2-dicyclohexylethane-1,2-dione. As soon as it is formed, the latter α-diketone undergoes either direct (noncatalytic) or nickel(I) salen-catalyzed reduction to its radical-anion, which can attack unreduced cyclohexanecarbonyl chloride; the resulting intermediate is further reduced and acylated to produce the tetramer.
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Bhattacharya D., Samide M. J., Peters D. Catalytic reduction of cyclohexanecarbonyl chloride with electrogenerated nickel(I) salen in acetonitrile // Journal of Electroanalytical Chemistry. 1998. Vol. 441. No. 1-2. pp. 103-107.
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Bhattacharya D., Samide M. J., Peters D. Catalytic reduction of cyclohexanecarbonyl chloride with electrogenerated nickel(I) salen in acetonitrile // Journal of Electroanalytical Chemistry. 1998. Vol. 441. No. 1-2. pp. 103-107.
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TY - JOUR
DO - 10.1016/s0022-0728(97)00418-x
UR - https://doi.org/10.1016/s0022-0728(97)00418-x
TI - Catalytic reduction of cyclohexanecarbonyl chloride with electrogenerated nickel(I) salen in acetonitrile
T2 - Journal of Electroanalytical Chemistry
AU - Bhattacharya, Deepta
AU - Samide, Michael J.
AU - Peters, Dennis
PY - 1998
DA - 1998/01/01
PB - Elsevier
SP - 103-107
IS - 1-2
VL - 441
SN - 1572-6657
SN - 1873-2569
ER -
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BibTex (up to 50 authors)
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@article{1998_Bhattacharya,
author = {Deepta Bhattacharya and Michael J. Samide and Dennis Peters},
title = {Catalytic reduction of cyclohexanecarbonyl chloride with electrogenerated nickel(I) salen in acetonitrile},
journal = {Journal of Electroanalytical Chemistry},
year = {1998},
volume = {441},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016/s0022-0728(97)00418-x},
number = {1-2},
pages = {103--107},
doi = {10.1016/s0022-0728(97)00418-x}
}
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MLA
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Bhattacharya, Deepta, et al. “Catalytic reduction of cyclohexanecarbonyl chloride with electrogenerated nickel(I) salen in acetonitrile.” Journal of Electroanalytical Chemistry, vol. 441, no. 1-2, Jan. 1998, pp. 103-107. https://doi.org/10.1016/s0022-0728(97)00418-x.