Journal of Fluorine Chemistry, volume 11, issue 3-4, pages 197-202

Enthalpies of solution of potassium hexafluororhenate(IV) and of potassium hexafluororuthenate(IV); single ion hydration enthalpies of the hexafluororhenate(IV) and hexafluororuthenate(IV) anions

Publication typeJournal Article
Publication date1978-03-01
scimago Q3
wos Q3
SJR0.355
CiteScore3.8
Impact factor1.7
ISSN00221139, 18733328
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Environmental Chemistry
Abstract
Enthalpies of solution of potassium hexafluororhenate(IV) and of potassium hexafluororuthenate(IV) in water at 298.2K have been determined by direct calorimetry. They are +63.0 ± 0.3 and +59.4 ± 1.5 kJ mol -1 respectively. From these results single ion hydration enthalpies of −999 and −967 kJ mol -1 have been estimated for the (gaseous) hexafluororhenate(IV) and hexafluororuthenate(IV) anions.
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