Reactions of 3-chloropentafluoropropene-1,2-oxide with bifunctional nucleophiles: a new route to chlorodifluoromethyl-substituted heterocycles
1
Department of Organic Chemistry, Institute of Chemical Technology, Technická 5, 16628 Prague 6, Czech Republic
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Тип публикации: Journal Article
Дата публикации: 2001-03-01
scimago Q3
wos Q3
БС2
SJR: 0.333
CiteScore: 3.7
Impact factor: 1.9
ISSN: 00221139, 18733328
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Environmental Chemistry
Краткое описание
An optimized preparation of 3-chloropentafluoropropene-1,2-oxide via alkaline peroxide epoxidation of 3-chloropentafluoro-1-propene under phase transfer catalysis conditions is described. The title epoxide was reacted with various bifunctional nitrogen nucleophiles to give five-, six- and seven-membered-ring heterocycles with pendant chlorodifluoromethyl groups. The described methodology represents a novel approach to chlorodifluoromethylated heterocycles.
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Kvíčala J., Hovorková P., Paleta O. Reactions of 3-chloropentafluoropropene-1,2-oxide with bifunctional nucleophiles: a new route to chlorodifluoromethyl-substituted heterocycles // Journal of Fluorine Chemistry. 2001. Vol. 108. No. 1. pp. 1-5.
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Kvíčala J., Hovorková P., Paleta O. Reactions of 3-chloropentafluoropropene-1,2-oxide with bifunctional nucleophiles: a new route to chlorodifluoromethyl-substituted heterocycles // Journal of Fluorine Chemistry. 2001. Vol. 108. No. 1. pp. 1-5.
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TY - JOUR
DO - 10.1016/s0022-1139(00)00403-6
UR - https://doi.org/10.1016/s0022-1139(00)00403-6
TI - Reactions of 3-chloropentafluoropropene-1,2-oxide with bifunctional nucleophiles: a new route to chlorodifluoromethyl-substituted heterocycles
T2 - Journal of Fluorine Chemistry
AU - Kvíčala, Jaroslav
AU - Hovorková, Pavla
AU - Paleta, Oldřich
PY - 2001
DA - 2001/03/01
PB - Elsevier
SP - 1-5
IS - 1
VL - 108
SN - 0022-1139
SN - 1873-3328
ER -
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@article{2001_Kvíčala,
author = {Jaroslav Kvíčala and Pavla Hovorková and Oldřich Paleta},
title = {Reactions of 3-chloropentafluoropropene-1,2-oxide with bifunctional nucleophiles: a new route to chlorodifluoromethyl-substituted heterocycles},
journal = {Journal of Fluorine Chemistry},
year = {2001},
volume = {108},
publisher = {Elsevier},
month = {mar},
url = {https://doi.org/10.1016/s0022-1139(00)00403-6},
number = {1},
pages = {1--5},
doi = {10.1016/s0022-1139(00)00403-6}
}
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Kvíčala, Jaroslav, et al. “Reactions of 3-chloropentafluoropropene-1,2-oxide with bifunctional nucleophiles: a new route to chlorodifluoromethyl-substituted heterocycles.” Journal of Fluorine Chemistry, vol. 108, no. 1, Mar. 2001, pp. 1-5. https://doi.org/10.1016/s0022-1139(00)00403-6.