volume 60 issue 2-3 pages 251-255

Reactions of tetrafluorophthalic and difluoropyromellitic acids with sulphur tetrafluoride

Publication typeJournal Article
Publication date1993-02-01
scimago Q3
wos Q3
SJR0.333
CiteScore3.7
Impact factor1.9
ISSN00221139, 18733328
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Environmental Chemistry
Abstract
Fluorination of tetrafluorophthalic acid ( 1 ) with an SF 4 /HF mixture at 190–300°C afforded,beside the expected perfluoro- o -xylene ( 2 ) and perfluoro- o -toluyl fluoride ( 4 ), considerableamounts of octafluoro-1,3-dihydroisobenzofuran ( 3 ). The reaction with difluoropyromelliticacid ( 5 ) at 190°C gave a mixture of perfluoro-2,4,5-trimethylbenzoyl fluoride ( 9 ),perfluoro-2,5-dimethylterephthaloyl difluoride ( 10a ), perfluoro-2,4-dimethylisophthaloyl difluoride( 10b ) and perfluoro-5-methyl-6-fluoroformyl-1,3-dihydroisobenzofuran ( 11 ), but at 300°C perfluorodurene ( 6 ), perfluoro-5,6-dimethyl-1,3-dihydroisobenzofuran ( 7 ) and perfluoro-2,4,5-trimethylbenzoyl fluoride ( 9 ) were obtained in a 3:1:0.8 ratio.
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Dmowski W. Reactions of tetrafluorophthalic and difluoropyromellitic acids with sulphur tetrafluoride // Journal of Fluorine Chemistry. 1993. Vol. 60. No. 2-3. pp. 251-255.
GOST all authors (up to 50) Copy
Dmowski W. Reactions of tetrafluorophthalic and difluoropyromellitic acids with sulphur tetrafluoride // Journal of Fluorine Chemistry. 1993. Vol. 60. No. 2-3. pp. 251-255.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1016/s0022-1139(00)80039-1
UR - https://doi.org/10.1016/s0022-1139(00)80039-1
TI - Reactions of tetrafluorophthalic and difluoropyromellitic acids with sulphur tetrafluoride
T2 - Journal of Fluorine Chemistry
AU - Dmowski, Wojciech
PY - 1993
DA - 1993/02/01
PB - Elsevier
SP - 251-255
IS - 2-3
VL - 60
SN - 0022-1139
SN - 1873-3328
ER -
BibTex |
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BibTex (up to 50 authors) Copy
@article{1993_Dmowski,
author = {Wojciech Dmowski},
title = {Reactions of tetrafluorophthalic and difluoropyromellitic acids with sulphur tetrafluoride},
journal = {Journal of Fluorine Chemistry},
year = {1993},
volume = {60},
publisher = {Elsevier},
month = {feb},
url = {https://doi.org/10.1016/s0022-1139(00)80039-1},
number = {2-3},
pages = {251--255},
doi = {10.1016/s0022-1139(00)80039-1}
}
MLA
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MLA Copy
Dmowski, Wojciech. “Reactions of tetrafluorophthalic and difluoropyromellitic acids with sulphur tetrafluoride.” Journal of Fluorine Chemistry, vol. 60, no. 2-3, Feb. 1993, pp. 251-255. https://doi.org/10.1016/s0022-1139(00)80039-1.