Etude comparative du comportement d'organometalliques allyliques et d'organolithiens satures vis a vis de carbures: RCH≡CHC≡CR′ et RC≡CC≡CR′ (R alcoyle, R′ H, alcoyle
1
Laboratoire de Synthèse Organique, Groupe de Recherches de Chimie Organique, Universitéde Poitiers, 86022 Poitiers France
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Publication type: Journal Article
Publication date: 1977-05-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Summary Reactive organometallic compounds such as allyl-zinc, -magnesium and -lithium and saturated lithium compounds are shown to readily undergo addition reactions with conjugated enynes and conjugated diynes: RCH CHC≡CH and RC≡CC≡CH; this reaction is regioselective and leads to conjugated dienes, conjugated enynes or allenes. The reactivity is reduced with conjugated enynes: RCH CHC≡CR′, but organo-magnesium and -lithium compounds lead to allenes. The reaction does not take place with conjugated diynes: RC≡CC≡CR′, under normal conditions.
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Total citations:
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Citations from 2024:
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(4%)
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Mauzé B. Etude comparative du comportement d'organometalliques allyliques et d'organolithiens satures vis a vis de carbures: RCH≡CHC≡CR′ et RC≡CC≡CR′ (R alcoyle, R′ H, alcoyle // Journal of Organometallic Chemistry. 1977. Vol. 131. No. 3. pp. 321-329.
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Mauzé B. Etude comparative du comportement d'organometalliques allyliques et d'organolithiens satures vis a vis de carbures: RCH≡CHC≡CR′ et RC≡CC≡CR′ (R alcoyle, R′ H, alcoyle // Journal of Organometallic Chemistry. 1977. Vol. 131. No. 3. pp. 321-329.
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TY - JOUR
DO - 10.1016/s0022-328x(00)84407-1
UR - https://doi.org/10.1016/s0022-328x(00)84407-1
TI - Etude comparative du comportement d'organometalliques allyliques et d'organolithiens satures vis a vis de carbures: RCH≡CHC≡CR′ et RC≡CC≡CR′ (R alcoyle, R′ H, alcoyle
T2 - Journal of Organometallic Chemistry
AU - Mauzé, Bernard
PY - 1977
DA - 1977/05/01
PB - Elsevier
SP - 321-329
IS - 3
VL - 131
SN - 0022-328X
SN - 1872-8561
ER -
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BibTex (up to 50 authors)
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@article{1977_Mauzé,
author = {Bernard Mauzé},
title = {Etude comparative du comportement d'organometalliques allyliques et d'organolithiens satures vis a vis de carbures: RCH≡CHC≡CR′ et RC≡CC≡CR′ (R alcoyle, R′ H, alcoyle},
journal = {Journal of Organometallic Chemistry},
year = {1977},
volume = {131},
publisher = {Elsevier},
month = {may},
url = {https://doi.org/10.1016/s0022-328x(00)84407-1},
number = {3},
pages = {321--329},
doi = {10.1016/s0022-328x(00)84407-1}
}
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MLA
Copy
Mauzé, Bernard. “Etude comparative du comportement d'organometalliques allyliques et d'organolithiens satures vis a vis de carbures: RCH≡CHC≡CR′ et RC≡CC≡CR′ (R alcoyle, R′ H, alcoyle.” Journal of Organometallic Chemistry, vol. 131, no. 3, May. 1977, pp. 321-329. https://doi.org/10.1016/s0022-328x(00)84407-1.