Enantiodifferentiation of olefinic groups in cis-1,2-divinylcyclohexane
Publication type: Journal Article
Publication date: 1996-11-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Chirality transfer from asymmetric ligands to the diene in ( η 4 - cis -1,2-divinylcyclohexane) rhodium complexes has been observed, leading to a slight excess of one of the two enantiomeric chair conformations of the cyclohexane ring. The importance of this phenomenon for the palladium-catalyzed oxidative cyclization of ( cis -1,22-divinylcyclohexane) using chiral carboxylates as nucleophiles is discussed.
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Nordström K., Moberg C., Heumann A. Enantiodifferentiation of olefinic groups in cis-1,2-divinylcyclohexane // Journal of Organometallic Chemistry. 1996. Vol. 525. No. 1-2. pp. 233-238.
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Nordström K., Moberg C., Heumann A. Enantiodifferentiation of olefinic groups in cis-1,2-divinylcyclohexane // Journal of Organometallic Chemistry. 1996. Vol. 525. No. 1-2. pp. 233-238.
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TY - JOUR
DO - 10.1016/s0022-328x(96)06440-6
UR - https://doi.org/10.1016/s0022-328x(96)06440-6
TI - Enantiodifferentiation of olefinic groups in cis-1,2-divinylcyclohexane
T2 - Journal of Organometallic Chemistry
AU - Nordström, Kerstin
AU - Moberg, C.
AU - Heumann, Andreas
PY - 1996
DA - 1996/11/01
PB - Elsevier
SP - 233-238
IS - 1-2
VL - 525
SN - 0022-328X
SN - 1872-8561
ER -
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BibTex (up to 50 authors)
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@article{1996_Nordström,
author = {Kerstin Nordström and C. Moberg and Andreas Heumann},
title = {Enantiodifferentiation of olefinic groups in cis-1,2-divinylcyclohexane},
journal = {Journal of Organometallic Chemistry},
year = {1996},
volume = {525},
publisher = {Elsevier},
month = {nov},
url = {https://doi.org/10.1016/s0022-328x(96)06440-6},
number = {1-2},
pages = {233--238},
doi = {10.1016/s0022-328x(96)06440-6}
}
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MLA
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Nordström, Kerstin, et al. “Enantiodifferentiation of olefinic groups in cis-1,2-divinylcyclohexane.” Journal of Organometallic Chemistry, vol. 525, no. 1-2, Nov. 1996, pp. 233-238. https://doi.org/10.1016/s0022-328x(96)06440-6.