Journal of Physics and Chemistry of Solids, volume 58, issue 4, pages 623-637

Nonisothermal transport properties of α-Ag2 + δS: Partial thermopowers of electrons and ions, the soret effect and heats of transport

Carsten Korte ¹

Jürgen Janek ¹

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Institut für Physikalische Chemie und Elektrochemie and Sonderforschungsbereich 173 der Universität Hannover, Callinstr. 3-3A, 30167 Hannover, Germany |

Publication type: Journal Article

Publication date: 1997-04-01

Elsevier

Journal: Journal of Physics and Chemistry of Solids

Quartile SCImago

Quartile WOS

Impact factor: 4

ISSN: 00223697, 00223697

DOI: 10.1016/s0022-3697(96)00172-2

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General Chemistry

Condensed Matter Physics

General Materials Science

Abstract

The ionic and electronic partial thermopowers and the Soret effect of α-Ag2 + δS (low temperature phase) have been studied as functions of temperature and deviation from stoichiometry δ by means of a nonisothermal galvanic cell. From a combination of these data with results from additional measurements of the partial entropy of silver metal in α-Ag2 + δS, the heat of transport of silver metal is determined. The measured transport properties are discussed in respect to the defect structure and isothermal transport properties of α-Ag2 + δS and information on the individual heats of transport of the mobile point defects is extracted. We observe a strong composition dependence of QAg∗ which can be explained within our formal analysis. The electronic properties can be interpreted within the model of a non-degenerate electron gas. The scattering factor of electronic defects in the statistical description of thermopower is equivalent to the electronic heat of transport in the phenomenological description.

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Citations by journals

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Advanced Functional Materials	Advanced Functional Materials, 2, 7.69% Advanced Functional Materials 2 publications, 7.69%
Physical Chemistry Chemical Physics	Physical Chemistry Chemical Physics, 2, 7.69% Physical Chemistry Chemical Physics 2 publications, 7.69%
Zeitschrift fur Physikalische Chemie	Zeitschrift fur Physikalische Chemie, 2, 7.69% Zeitschrift fur Physikalische Chemie 2 publications, 7.69%
Journal of Nuclear Materials	Journal of Nuclear Materials, 1, 3.85% Journal of Nuclear Materials 1 publication, 3.85%
International Journal of Heat and Mass Transfer	International Journal of Heat and Mass Transfer, 1, 3.85% International Journal of Heat and Mass Transfer 1 publication, 3.85%
International Journal of Inorganic Materials	International Journal of Inorganic Materials, 1, 3.85% International Journal of Inorganic Materials 1 publication, 3.85%
Nanomaterials	Nanomaterials, 1, 3.85% Nanomaterials 1 publication, 3.85%
Nature Materials	Nature Materials, 1, 3.85% Nature Materials 1 publication, 3.85%
Nature Communications	Nature Communications, 1, 3.85% Nature Communications 1 publication, 3.85%
Journal of Alloys and Compounds	Journal of Alloys and Compounds, 1, 3.85% Journal of Alloys and Compounds 1 publication, 3.85%
Electrochimica Acta	Electrochimica Acta, 1, 3.85% Electrochimica Acta 1 publication, 3.85%
Journal of Solid State Chemistry	Journal of Solid State Chemistry, 1, 3.85% Journal of Solid State Chemistry 1 publication, 3.85%
Sensors and Actuators, B: Chemical	Sensors and Actuators, B: Chemical, 1, 3.85% Sensors and Actuators, B: Chemical 1 publication, 3.85%
Materials Letters	Materials Letters, 1, 3.85% Materials Letters 1 publication, 3.85%
Solid State Sciences	Solid State Sciences, 1, 3.85% Solid State Sciences 1 publication, 3.85%
Physica Status Solidi (A) Applications and Materials Science	Physica Status Solidi (A) Applications and Materials Science, 1, 3.85% Physica Status Solidi (A) Applications and Materials Science 1 publication, 3.85%
Advanced Science	Advanced Science, 1, 3.85% Advanced Science 1 publication, 3.85%
Inorganic Chemistry	Inorganic Chemistry, 1, 3.85% Inorganic Chemistry 1 publication, 3.85%
Journal of Materials Chemistry C	Journal of Materials Chemistry C, 1, 3.85% Journal of Materials Chemistry C 1 publication, 3.85%
Journal of the Korean Ceramic Society	Journal of the Korean Ceramic Society, 1, 3.85% Journal of the Korean Ceramic Society 1 publication, 3.85%
Lecture Notes in Physics	Lecture Notes in Physics, 1, 3.85% Lecture Notes in Physics 1 publication, 3.85%
Russian Chemical Reviews	Russian Chemical Reviews, 1, 3.85% Russian Chemical Reviews 1 publication, 3.85%
Small Structures	Small Structures, 1, 3.85% Small Structures 1 publication, 3.85%
	1 2

Citations by publishers

	1 2 3 4 5 6 7 8 9
Elsevier	Elsevier, 9, 34.62% Elsevier 9 publications, 34.62%
Wiley	Wiley, 5, 19.23% Wiley 5 publications, 19.23%
Springer Nature	Springer Nature, 3, 11.54% Springer Nature 3 publications, 11.54%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 3, 11.54% Royal Society of Chemistry (RSC) 3 publications, 11.54%
Walter de Gruyter	Walter de Gruyter, 2, 7.69% Walter de Gruyter 2 publications, 7.69%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 1, 3.85% Multidisciplinary Digital Publishing Institute (MDPI) 1 publication, 3.85%
American Chemical Society (ACS)	American Chemical Society (ACS), 1, 3.85% American Chemical Society (ACS) 1 publication, 3.85%
Korean Ceramic Society	Korean Ceramic Society, 1, 3.85% Korean Ceramic Society 1 publication, 3.85%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 3.85% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 3.85%
	1 2 3 4 5 6 7 8 9

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Korte C., Janek J. Nonisothermal transport properties of α-Ag2 + δS: Partial thermopowers of electrons and ions, the soret effect and heats of transport // Journal of Physics and Chemistry of Solids. 1997. Vol. 58. No. 4. pp. 623-637.

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TY - JOUR

DO - 10.1016/s0022-3697(96)00172-2

UR - https://doi.org/10.1016/s0022-3697(96)00172-2

TI - Nonisothermal transport properties of α-Ag2 + δS: Partial thermopowers of electrons and ions, the soret effect and heats of transport

T2 - Journal of Physics and Chemistry of Solids

AU - Korte, Carsten

AU - Janek, Jürgen

PY - 1997

DA - 1997/04/01 00:00:00

PB - Elsevier

SP - 623-637

IS - 4

VL - 58

SN - 0022-3697

ER -

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@article{1997_Korte,

author = {Carsten Korte and Jürgen Janek},

title = {Nonisothermal transport properties of α-Ag2 + δS: Partial thermopowers of electrons and ions, the soret effect and heats of transport},

journal = {Journal of Physics and Chemistry of Solids},

year = {1997},

volume = {58},

publisher = {Elsevier},

month = {apr},

url = {https://doi.org/10.1016/s0022-3697(96)00172-2},

number = {4},

pages = {623--637},

doi = {10.1016/s0022-3697(96)00172-2}

}

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Korte, Carsten, and Jürgen Janek. “Nonisothermal transport properties of α-Ag2 + δS: Partial thermopowers of electrons and ions, the soret effect and heats of transport.” Journal of Physics and Chemistry of Solids, vol. 58, no. 4, Apr. 1997, pp. 623-637. https://doi.org/10.1016/s0022-3697(96)00172-2.

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Elsevier

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Journal of Physics and Chemistry of Solids

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00223697 (Electronic)
00223697 (Print)