Tetrahedron

, том 57 , издание 20 , страницы 4271-4276

Synthesis of (Z)-1-phenylseleno-1,4-diorganyl-1-buten-3-ynes: hydroselenation of symmetrical and unsymmetrical 1,4-diorganyl-1,3-butadiynes

Тип публикации: Journal Article

Дата публикации: 2001-05-01

Elsevier

Tetrahedron

scimago Q3

wos Q2

БС2

SJR: 0.426

CiteScore: 4.1

Impact factor: 2.2

ISSN: 00404020, 14645416

DOI: 10.1016/s0040-4020(01)00337-4

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Organic Chemistry

Drug Discovery

Biochemistry

Краткое описание

The hydroselenation of 1-organyl-1,3-butadiynes and 1,4-diorganyl-1,3-butadiynes with the sodium phenylselenolate anion, which was generated in situ by reacting diphenyl diselenide with NaBH 4 in aqueous ethanol, results in the regio-, stereo- and chemoselective formation the 1-phenylseleno-4-organyl-1-buten-3-ynes and 1-phenylseleno-1,4-diorganyl-1-buten-3-ynes of Z configuration respectively. The lack of selectivity with the 2-hydroxy-2-methyl-3,5-dodecadiyne was observed and the obtained product structures were studied in detail. Graphic

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Dabdoub M. J. et al. Synthesis of (Z)-1-phenylseleno-1,4-diorganyl-1-buten-3-ynes: hydroselenation of symmetrical and unsymmetrical 1,4-diorganyl-1,3-butadiynes // Tetrahedron. 2001. Vol. 57. No. 20. pp. 4271-4276.

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Dabdoub M. J., Baroni A. C., Alves D. C. B., Gianeti T. R., Hurtado G. R. Synthesis of (Z)-1-phenylseleno-1,4-diorganyl-1-buten-3-ynes: hydroselenation of symmetrical and unsymmetrical 1,4-diorganyl-1,3-butadiynes // Tetrahedron. 2001. Vol. 57. No. 20. pp. 4271-4276.

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TY - JOUR

DO - 10.1016/s0040-4020(01)00337-4

UR - https://doi.org/10.1016/s0040-4020(01)00337-4

TI - Synthesis of (Z)-1-phenylseleno-1,4-diorganyl-1-buten-3-ynes: hydroselenation of symmetrical and unsymmetrical 1,4-diorganyl-1,3-butadiynes

T2 - Tetrahedron

AU - Dabdoub, Miguel J

AU - Baroni, Adriano C.M

AU - Alves, Diego C. B.

AU - Gianeti, Thiago R

AU - Hurtado, Gabriela R

PY - 2001

DA - 2001/05/01

PB - Elsevier

SP - 4271-4276

IS - 20

VL - 57

SN - 0040-4020

SN - 1464-5416

ER -

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@article{2001_Dabdoub,

author = {Miguel J Dabdoub and Adriano C.M Baroni and Diego C. B. Alves and Thiago R Gianeti and Gabriela R Hurtado},

title = {Synthesis of (Z)-1-phenylseleno-1,4-diorganyl-1-buten-3-ynes: hydroselenation of symmetrical and unsymmetrical 1,4-diorganyl-1,3-butadiynes},

journal = {Tetrahedron},

year = {2001},

volume = {57},

publisher = {Elsevier},

month = {may},

url = {https://doi.org/10.1016/s0040-4020(01)00337-4},

number = {20},

pages = {4271--4276},

doi = {10.1016/s0040-4020(01)00337-4}

}

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Dabdoub, Miguel J., et al. “Synthesis of (Z)-1-phenylseleno-1,4-diorganyl-1-buten-3-ynes: hydroselenation of symmetrical and unsymmetrical 1,4-diorganyl-1,3-butadiynes.” Tetrahedron, vol. 57, no. 20, May. 2001, pp. 4271-4276. https://doi.org/10.1016/s0040-4020(01)00337-4.

Издатель

Elsevier

Журнал

Tetrahedron

scimago Q3

wos Q2

БС2

SJR

0.426

CiteScore

4.1

Impact factor

2.2

ISSN

00404020 (Print)

14645416 (Electronic)