The synthesis and chemical reactivity of 3-chloro-6-(2-pyrrolyl)pyridazine
Publication type: Journal Article
Publication date: 1998-08-01
scimago Q3
wos Q2
SJR: 0.426
CiteScore: 4.1
Impact factor: 2.2
ISSN: 00404020, 14645416
Organic Chemistry
Drug Discovery
Biochemistry
Abstract
3,6-Dichloropyridazine and 1-alkyl-3,6-dichloropyridazinium cations react with pyrrolylmagnesium bromide to produce 3-chloro-6-(2-pyrrolyl)pyridazine. Further reaction with other nucleophiles is slow, but is enhanced by quaternisation of the 2-N atom. 3,6-Di(2-pyrrolyl)pyridazine could not be obtained by this route. 3,6-Dichloropyridazine and 1-alkyl-3,6-dichloropyridazinium cations react with pyrrolylmagnesium bromide to produce 1 . Further reaction of 1 with other nucleophiles is slow, but is enhanced by quaternisation of the 2-N atom. 3,6-Di(2-pyrrolyl)pyridazine could not be obtained by this route.
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Jones R., Whitmore A. P. The synthesis and chemical reactivity of 3-chloro-6-(2-pyrrolyl)pyridazine // Tetrahedron. 1998. Vol. 54. No. 33. pp. 9519-9528.
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Jones R., Whitmore A. P. The synthesis and chemical reactivity of 3-chloro-6-(2-pyrrolyl)pyridazine // Tetrahedron. 1998. Vol. 54. No. 33. pp. 9519-9528.
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RIS
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TY - JOUR
DO - 10.1016/s0040-4020(98)00513-4
UR - https://doi.org/10.1016/s0040-4020(98)00513-4
TI - The synthesis and chemical reactivity of 3-chloro-6-(2-pyrrolyl)pyridazine
T2 - Tetrahedron
AU - Jones, R.B.
AU - Whitmore, Alexander P
PY - 1998
DA - 1998/08/01
PB - Elsevier
SP - 9519-9528
IS - 33
VL - 54
SN - 0040-4020
SN - 1464-5416
ER -
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BibTex (up to 50 authors)
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@article{1998_Jones,
author = {R.B. Jones and Alexander P Whitmore},
title = {The synthesis and chemical reactivity of 3-chloro-6-(2-pyrrolyl)pyridazine},
journal = {Tetrahedron},
year = {1998},
volume = {54},
publisher = {Elsevier},
month = {aug},
url = {https://doi.org/10.1016/s0040-4020(98)00513-4},
number = {33},
pages = {9519--9528},
doi = {10.1016/s0040-4020(98)00513-4}
}
Cite this
MLA
Copy
Jones, R.B., and Alexander P Whitmore. “The synthesis and chemical reactivity of 3-chloro-6-(2-pyrrolyl)pyridazine.” Tetrahedron, vol. 54, no. 33, Aug. 1998, pp. 9519-9528. https://doi.org/10.1016/s0040-4020(98)00513-4.