Tetrahedron Letters, volume 30, issue 12, pages 1479-1482
The solvolysis of N-acetoxy-4-acetylaminostilbene: Irreversible formation of nitrenium ions
Constantinos Nicolaou
1
,
Graham J. C. Underwood
1
Publication type: Journal Article
Publication date: 1989-01-01
Journal:
Tetrahedron Letters
scimago Q3
wos Q3
SJR: 0.323
CiteScore: 3.5
Impact factor: 1.5
ISSN: 00404039, 18733581
Organic Chemistry
Drug Discovery
Biochemistry
Abstract
Extensive kinetic studies and product analysis, coupled with 0–18 labeling experiments have shown that the solvolysis of N-acetoxy-4-acetylaminostilbene in buffered aqueous acetone proceeds via irreversible nitrenium ion formation. The conflict between this conclusion and that of a previous study is explained
Found
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