Tetrahedron Letters, volume 30, issue 12, pages 1479-1482

The solvolysis of N-acetoxy-4-acetylaminostilbene: Irreversible formation of nitrenium ions

Publication typeJournal Article
Publication date1989-01-01
scimago Q3
wos Q3
SJR0.323
CiteScore3.5
Impact factor1.5
ISSN00404039, 18733581
Organic Chemistry
Drug Discovery
Biochemistry
Abstract
Extensive kinetic studies and product analysis, coupled with 0–18 labeling experiments have shown that the solvolysis of N-acetoxy-4-acetylaminostilbene in buffered aqueous acetone proceeds via irreversible nitrenium ion formation. The conflict between this conclusion and that of a previous study is explained
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