, volume 84 , issue 1-3 , pages 95-96

Chemical synthesis and characterization of fluoro-substituted polyanilines

Angela H Kwon ¹

Jeanine A Conklin ²

Michael Makhinson ¹

Richard Kaner ¹

Hide authors affiliations Show authors affiliations: 2 affiliations

Department of Chemistry and Biochemistry and Solid State Science Center, University of California, Los Angeles, CA 90095-1569, USA |

Surface Modification Branch, US Naval Research Lab, Washington, DC 20375-5345, USA |

Publication type: Journal Article

Publication date: 1997-01-01

Elsevier

Synthetic Metals

scimago Q1

wos Q2

SJR: 0.787

CiteScore: 8.3

Impact factor: 4.6

ISSN: 03796779

DOI: 10.1016/s0379-6779(96)03853-2

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Materials Chemistry

Metals and Alloys

Electronic, Optical and Magnetic Materials

Condensed Matter Physics

Mechanical Engineering

Mechanics of Materials

Abstract

Polyfluoroanilines can be synthesized chemically from fluorine-substituted aniline monomers by an acid assisted persulfate initiated polymerization route typically used for polyaniline synthesis. Successful polymerizations of 2- and 3-fluoroanilines have been accomplished. Typical polymer yields are between 3–7% by weight. In contrast, poly(4-fluoroaniline) undergoes dehalogenation during polymerization, where the fluorine is displaced allowing for the more favorable head-to-tail polymerization of aniline. Characterizations of the polymer products have been carried out using UV-VIS, FT-IR, and NMR spectroscopies, differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), and relative solubilities of the polyfluoroaniline powders determined in various organic solvents.

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M. Ahmet

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Middle East Technical University

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GOST |

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GOST Copy

Kwon A. H. et al. Chemical synthesis and characterization of fluoro-substituted polyanilines // Synthetic Metals. 1997. Vol. 84. No. 1-3. pp. 95-96.

GOST all authors (up to 50) Copy

Kwon A. H., Conklin J. A., Makhinson M., Kaner R. Chemical synthesis and characterization of fluoro-substituted polyanilines // Synthetic Metals. 1997. Vol. 84. No. 1-3. pp. 95-96.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1016/s0379-6779(96)03853-2

UR - https://doi.org/10.1016/s0379-6779(96)03853-2

TI - Chemical synthesis and characterization of fluoro-substituted polyanilines

T2 - Synthetic Metals

AU - Kwon, Angela H

AU - Conklin, Jeanine A

AU - Makhinson, Michael

AU - Kaner, Richard

PY - 1997

DA - 1997/01/01

PB - Elsevier

SP - 95-96

IS - 1-3

VL - 84

SN - 0379-6779

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{1997_Kwon,

author = {Angela H Kwon and Jeanine A Conklin and Michael Makhinson and Richard Kaner},

title = {Chemical synthesis and characterization of fluoro-substituted polyanilines},

journal = {Synthetic Metals},

year = {1997},

volume = {84},

publisher = {Elsevier},

month = {jan},

url = {https://doi.org/10.1016/s0379-6779(96)03853-2},

number = {1-3},

pages = {95--96},

doi = {10.1016/s0379-6779(96)03853-2}

}

MLA

Cite this

MLA Copy

Kwon, Angela H., et al. “Chemical synthesis and characterization of fluoro-substituted polyanilines.” Synthetic Metals, vol. 84, no. 1-3, Jan. 1997, pp. 95-96. https://doi.org/10.1016/s0379-6779(96)03853-2.

Publisher

Elsevier

Journal

Synthetic Metals

scimago Q1

wos Q2

SJR

0.787

CiteScore

8.3

Impact factor

4.6

ISSN

03796779 (Print)