Electrocatalytic conversion of methane to syngas over Ni electrode in a solid oxide electrolyte cell
Publication type: Journal Article
Publication date: 1997-12-01
scimago Q2
wos Q2
SJR: 1.000
CiteScore: 8.6
Impact factor: 4.8
ISSN: 0926860X, 18733875
Catalysis
Process Chemistry and Technology
Abstract
Electrocatalytic conversion of metane in a cell with a solid oxygen conducting electrolyte: CH 4 , Ni|0.9ZrO 2 + 0.1Y 2 O 3 |Pt + PrO 2 , air was studied at the temperature range 750°C–850°C. The Ni electrode was found to be an active electrode-catalyst for partial oxidation of CH 4 to syngas with the concentration ratio [H 2 ] : [CO]≈2 . The CH 4 conversion and CO selectivity attained 85%–95% and 90%–95%, respectively, at 800°C–850°C. Under these conditions the Ni electrode-catalyst was stable to coking and had a negative value of electrode potential with respect to an air counter electrode. The direct partial oxidation mechanism was shown to be the most probable for the electrocatalytic conversion of CH 4 to syngas.
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GOST
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Galvita V. V. et al. Electrocatalytic conversion of methane to syngas over Ni electrode in a solid oxide electrolyte cell // Applied Catalysis A: General. 1997. Vol. 165. No. 1-2. pp. 301-308.
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Galvita V. V., Belyaev V., Demin A. K., Sobyanin V. A. Electrocatalytic conversion of methane to syngas over Ni electrode in a solid oxide electrolyte cell // Applied Catalysis A: General. 1997. Vol. 165. No. 1-2. pp. 301-308.
Cite this
RIS
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TY - JOUR
DO - 10.1016/s0926-860x(97)00210-x
UR - https://doi.org/10.1016/s0926-860x(97)00210-x
TI - Electrocatalytic conversion of methane to syngas over Ni electrode in a solid oxide electrolyte cell
T2 - Applied Catalysis A: General
AU - Galvita, Vladimir V.
AU - Belyaev, V.D
AU - Demin, Anatoly K.
AU - Sobyanin, V. A.
PY - 1997
DA - 1997/12/01
PB - Elsevier
SP - 301-308
IS - 1-2
VL - 165
SN - 0926-860X
SN - 1873-3875
ER -
Cite this
BibTex (up to 50 authors)
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@article{1997_Galvita,
author = {Vladimir V. Galvita and V.D Belyaev and Anatoly K. Demin and V. A. Sobyanin},
title = {Electrocatalytic conversion of methane to syngas over Ni electrode in a solid oxide electrolyte cell},
journal = {Applied Catalysis A: General},
year = {1997},
volume = {165},
publisher = {Elsevier},
month = {dec},
url = {https://doi.org/10.1016/s0926-860x(97)00210-x},
number = {1-2},
pages = {301--308},
doi = {10.1016/s0926-860x(97)00210-x}
}
Cite this
MLA
Copy
Galvita, Vladimir V., et al. “Electrocatalytic conversion of methane to syngas over Ni electrode in a solid oxide electrolyte cell.” Applied Catalysis A: General, vol. 165, no. 1-2, Dec. 1997, pp. 301-308. https://doi.org/10.1016/s0926-860x(97)00210-x.