Kinetics of the Mono-esterification Between Terephthalic Acid and 1,4-Butanediol
Publication type: Journal Article
Publication date: 2010-01-01
scimago Q1
wos Q2
SJR: 0.781
CiteScore: 7.5
Impact factor: 3.7
ISSN: 10049541, 2210321X
General Chemistry
Biochemistry
General Chemical Engineering
Environmental Engineering
Abstract
The chemical kinetics of the monoesterification between terephthalic acid (TPA) and 1,4-butanediol (BDO) catalyzed by a metallo-organic compound was studied using the initial rate method. The experiments were carried out in the temperature range of 463-483 K, and butylhydroxyoxo-stannane (BuSnOOH) and tetrabutyl titanate [Ti(OBu) 4 ] were used as catalyst respectively. The initial rates of the reaction catalyzed by BuSnOOH or Ti(OBu) 4 were measured at a series of initial concentrations of BDO (or TPA) with the concentration of TPA (or BDO) kept constant. The reaction orders of reagents were determined by the initial rate method. The results indicate that the reaction order for TPA is related with the species of catalyst and it is 2 and 0.7 for BuSnOOH and Ti(OBu) 4 respectively. However, the order for BDO is the same 0.9 for the two catalysts. Furthermore, the effects of temperature and catalyst concentration are investigated, and the activation energies and the reaction rate constants for the two catalysts were determined.
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Total citations:
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Citations from 2024:
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Tian W. et al. Kinetics of the Mono-esterification Between Terephthalic Acid and 1,4-Butanediol // Chinese Journal of Chemical Engineering. 2010. Vol. 18. No. 3. pp. 391-396.
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Tian W., Zeng Z., Xue W., Li Y., Zhang T. Kinetics of the Mono-esterification Between Terephthalic Acid and 1,4-Butanediol // Chinese Journal of Chemical Engineering. 2010. Vol. 18. No. 3. pp. 391-396.
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RIS
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TY - JOUR
DO - 10.1016/s1004-9541(10)60236-4
UR - https://doi.org/10.1016/s1004-9541(10)60236-4
TI - Kinetics of the Mono-esterification Between Terephthalic Acid and 1,4-Butanediol
T2 - Chinese Journal of Chemical Engineering
AU - Tian, Wenyu
AU - Zeng, Zuoxiang
AU - Xue, Weilan
AU - Li, Yingbin
AU - Zhang, Tianyu
PY - 2010
DA - 2010/01/01
PB - Elsevier
SP - 391-396
IS - 3
VL - 18
SN - 1004-9541
SN - 2210-321X
ER -
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BibTex (up to 50 authors)
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@article{2010_Tian,
author = {Wenyu Tian and Zuoxiang Zeng and Weilan Xue and Yingbin Li and Tianyu Zhang},
title = {Kinetics of the Mono-esterification Between Terephthalic Acid and 1,4-Butanediol},
journal = {Chinese Journal of Chemical Engineering},
year = {2010},
volume = {18},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016/s1004-9541(10)60236-4},
number = {3},
pages = {391--396},
doi = {10.1016/s1004-9541(10)60236-4}
}
Cite this
MLA
Copy
Tian, Wenyu, et al. “Kinetics of the Mono-esterification Between Terephthalic Acid and 1,4-Butanediol.” Chinese Journal of Chemical Engineering, vol. 18, no. 3, Jan. 2010, pp. 391-396. https://doi.org/10.1016/s1004-9541(10)60236-4.