1,3-Butadiene telomerization with methanol catalyzed by heterogenized palladium(II) complexes anchored to polymer-bound bis(diphenylphosphino)methane moieties
Publication type: Journal Article
Publication date: 1999-03-05
SJR: —
CiteScore: —
Impact factor: —
ISSN: 13811169
Catalysis
Physical and Theoretical Chemistry
Process Chemistry and Technology
Abstract
The telomerization of 1,3-butadiene with methanol in the presence of heterogenized palladium(II) catalysts, obtained by anchoring the metal on both a styrene/divinylbenzene macroporous resin and a linear poly(styrene) functionalized with bis(diphenylphosphino)methane moieties, is reported. In particular, the activity and selectivity to telomers of the above catalytic systems is compared with the corresponding homogeneous counterpart and with those previously obtained with analogous heterogenized systems via polymer-bound 1,3-bis(diphenylphosphino)propane moieties. The effect of a methoxide promoter is also studied. Finally, the performances and metal leaching in solution of the above heterogenized catalysts are checked after several reaction cycles in order to verify their real heterogeneous character.
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15
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15
Citations from 2024:
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GOST
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Benvenuti F. 1,3-Butadiene telomerization with methanol catalyzed by heterogenized palladium(II) complexes anchored to polymer-bound bis(diphenylphosphino)methane moieties // Journal of Molecular Catalysis A Chemical. 1999. Vol. 139. No. 2-3. pp. 177-187.
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Benvenuti F. 1,3-Butadiene telomerization with methanol catalyzed by heterogenized palladium(II) complexes anchored to polymer-bound bis(diphenylphosphino)methane moieties // Journal of Molecular Catalysis A Chemical. 1999. Vol. 139. No. 2-3. pp. 177-187.
Cite this
RIS
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TY - JOUR
DO - 10.1016/s1381-1169(98)00215-5
UR - https://doi.org/10.1016/s1381-1169(98)00215-5
TI - 1,3-Butadiene telomerization with methanol catalyzed by heterogenized palladium(II) complexes anchored to polymer-bound bis(diphenylphosphino)methane moieties
T2 - Journal of Molecular Catalysis A Chemical
AU - Benvenuti, F
PY - 1999
DA - 1999/03/05
PB - Elsevier
SP - 177-187
IS - 2-3
VL - 139
SN - 1381-1169
ER -
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BibTex (up to 50 authors)
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@article{1999_Benvenuti,
author = {F Benvenuti},
title = {1,3-Butadiene telomerization with methanol catalyzed by heterogenized palladium(II) complexes anchored to polymer-bound bis(diphenylphosphino)methane moieties},
journal = {Journal of Molecular Catalysis A Chemical},
year = {1999},
volume = {139},
publisher = {Elsevier},
month = {mar},
url = {https://doi.org/10.1016/s1381-1169(98)00215-5},
number = {2-3},
pages = {177--187},
doi = {10.1016/s1381-1169(98)00215-5}
}
Cite this
MLA
Copy
Benvenuti, F.. “1,3-Butadiene telomerization with methanol catalyzed by heterogenized palladium(II) complexes anchored to polymer-bound bis(diphenylphosphino)methane moieties.” Journal of Molecular Catalysis A Chemical, vol. 139, no. 2-3, Mar. 1999, pp. 177-187. https://doi.org/10.1016/s1381-1169(98)00215-5.