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Catalysis Communications

, том 3 , издание 5 , страницы 213-219

Hydroformylation of ethylene in supercritical carbon dioxide using Ru3(CO)12 as a catalyst precursor

Тип публикации: Journal Article

Дата публикации: 2002-05-01

Elsevier

Catalysis Communications

SCImago Q2

WOS Q2

SJR: 0.762

CiteScore: 7.9

Impact factor: 5.5

ISSN: 15667367

DOI: 10.1016/s1566-7367(02)00093-6

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General Chemistry

Catalysis

Process Chemistry and Technology

Краткое описание

The homogeneous catalytic hydroformylation of ethylene in supercritical carbon dioxide was studied using the trinuclear carbonyl cluster Ru 3 (CO) 12 as a catalyst precursor. Ru 3 (CO) 12 was found to be sufficiently soluble in supercritical CO 2 . The hydroformylation experiments were carried out in the temperature range between 60 and 125 °C and in the pressure range from 224 to 408 atm. The catalyst was inactive below 70 °C, but above this value the activity increased with temperature. After an induction period of several hours the reaction rate increased exponentially. The effect of the density of scCO 2 on the reaction rate was also investigated.

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Журналы

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Journal of Supercritical Fluids	Journal of Supercritical Fluids, 3, 16.67% Journal of Supercritical Fluids 3 публикации, 16.67%
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Journal of the Japan Institute of Energy	Journal of the Japan Institute of Energy, 1, 5.56% Journal of the Japan Institute of Energy 1 публикация, 5.56%
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ГОСТ |

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Erkey C. et al. Hydroformylation of ethylene in supercritical carbon dioxide using Ru3(CO)12 as a catalyst precursor // Catalysis Communications. 2002. Vol. 3. No. 5. pp. 213-219.

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Erkey C., Lozano Diz E., Süss-Fink G., Xing D. Hydroformylation of ethylene in supercritical carbon dioxide using Ru3(CO)12 as a catalyst precursor // Catalysis Communications. 2002. Vol. 3. No. 5. pp. 213-219.

RIS |

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RIS Скопировать

TY - JOUR

DO - 10.1016/s1566-7367(02)00093-6

UR - https://doi.org/10.1016/s1566-7367(02)00093-6

TI - Hydroformylation of ethylene in supercritical carbon dioxide using Ru3(CO)12 as a catalyst precursor

T2 - Catalysis Communications

AU - Erkey, Can

AU - Lozano Diz, Enrique

AU - Süss-Fink, Georg

AU - Xing, Dong

PY - 2002

DA - 2002/05/01

PB - Elsevier

SP - 213-219

IS - 5

VL - 3

SN - 1566-7367

ER -

BibTex |

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@article{2002_Erkey,

author = {Can Erkey and Enrique Lozano Diz and Georg Süss-Fink and Dong Xing},

title = {Hydroformylation of ethylene in supercritical carbon dioxide using Ru3(CO)12 as a catalyst precursor},

journal = {Catalysis Communications},

year = {2002},

volume = {3},

publisher = {Elsevier},

month = {may},

url = {https://doi.org/10.1016/s1566-7367(02)00093-6},

number = {5},

pages = {213--219},

doi = {10.1016/s1566-7367(02)00093-6}

}

MLA

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MLA Скопировать

Erkey, Can, et al. “Hydroformylation of ethylene in supercritical carbon dioxide using Ru3(CO)12 as a catalyst precursor.” Catalysis Communications, vol. 3, no. 5, May. 2002, pp. 213-219. https://doi.org/10.1016/s1566-7367(02)00093-6.

Издатель

Elsevier

Журнал

Catalysis Communications

SCImago Q2

WOS Q2

SJR

0.762

CiteScore

7.9

Impact factor

5.5

ISSN

15667367 (Print)

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