Synergetic effect between Ni2P/γ-Al2O3 and MoS2/γ-Al2O3 catalysts on their performance in hydrodenitrogenation of quinoline
Publication type: Journal Article
Publication date: 2013-06-01
scimago Q3
SJR: 0.398
CiteScore: 3.4
Impact factor: —
ISSN: 18725813, 02532409
General Medicine
Abstract
The synergetic effect between Ni2P/Al2O3 and MoS2/Al2O3 catalysts on their performance in the hydrodenitrogenation of quinoline was proved by a simplified experimental design and explained by the remote control model through a migration of hydrogen spillover. The results indicated that the synergism factor of Ni2P and MoS2 is slightly higher than that of NiSx and MoS2; it decreases with the increase of reaction temperature. Since the spillover hydrogen with Ni2P can increase the amount of hydrogenation active sites of MoS2, the hydrogenation rate of 1,2,3,4-tetrahydroquinoline and 5,6,7,8-tetrahydroquinoline to decahydroquinoline over the Ni2P/Al2O3 and MoS2/Al2O3 catalyst system is then greatly enhanced; as a result, Ni2P is a superior promoter for MoS2 catalyst for hydrodenitrogenation.
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Liu L. et al. Synergetic effect between Ni2P/γ-Al2O3 and MoS2/γ-Al2O3 catalysts on their performance in hydrodenitrogenation of quinoline // Journal of Fuel Chemistry and Technology. 2013. Vol. 41. No. 6. pp. 698-702.
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Liu L., Liu S., Chai Y., Liu Y., Liu C. Synergetic effect between Ni2P/γ-Al2O3 and MoS2/γ-Al2O3 catalysts on their performance in hydrodenitrogenation of quinoline // Journal of Fuel Chemistry and Technology. 2013. Vol. 41. No. 6. pp. 698-702.
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TY - JOUR
DO - 10.1016/s1872-5813(13)60033-x
UR - https://doi.org/10.1016/s1872-5813(13)60033-x
TI - Synergetic effect between Ni2P/γ-Al2O3 and MoS2/γ-Al2O3 catalysts on their performance in hydrodenitrogenation of quinoline
T2 - Journal of Fuel Chemistry and Technology
AU - Liu, Lihua
AU - Liu, Shuqun
AU - Chai, Yong-Ming
AU - Liu, Yunqi
AU - Liu, Chenguang
PY - 2013
DA - 2013/06/01
PB - Elsevier
SP - 698-702
IS - 6
VL - 41
SN - 1872-5813
SN - 0253-2409
ER -
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BibTex (up to 50 authors)
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@article{2013_Liu,
author = {Lihua Liu and Shuqun Liu and Yong-Ming Chai and Yunqi Liu and Chenguang Liu},
title = {Synergetic effect between Ni2P/γ-Al2O3 and MoS2/γ-Al2O3 catalysts on their performance in hydrodenitrogenation of quinoline},
journal = {Journal of Fuel Chemistry and Technology},
year = {2013},
volume = {41},
publisher = {Elsevier},
month = {jun},
url = {https://doi.org/10.1016/s1872-5813(13)60033-x},
number = {6},
pages = {698--702},
doi = {10.1016/s1872-5813(13)60033-x}
}
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MLA
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Liu, Lihua, et al. “Synergetic effect between Ni2P/γ-Al2O3 and MoS2/γ-Al2O3 catalysts on their performance in hydrodenitrogenation of quinoline.” Journal of Fuel Chemistry and Technology, vol. 41, no. 6, Jun. 2013, pp. 698-702. https://doi.org/10.1016/s1872-5813(13)60033-x.