Chemical Physics Letters, volume 99, issue 1, pages 7-10
Photochemical reduction of carbonate to formaldehyde on TiO2 powder
Publication type: Journal Article
Publication date: 1983-07-01
Journal:
Chemical Physics Letters
Quartile SCImago
Q2
Quartile WOS
Q2
Impact factor: 2.8
ISSN: 00092614
Physical and Theoretical Chemistry
General Physics and Astronomy
Abstract
Photochemical reactions at semiconductor particle surfaces have been used to drive energy uphill reactions to store light energy. Carbonate radical anion was found to be intermediate when carbonate was used to intercept the photogenerated hole on TiO 2 by exciting with light energy of more than 3.2 eV. The carbonate anion radical undergoes secondary reactions on the surface to give formaldehyde. The chemical energy stored in this reaction is 580 kj/mole. The quantum yield for the formation of HCHO is 4 × 10 −3 , but extended irradiation leads to loss of formaldehyde.
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Citations by publishers
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2
4
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10
12
14
16
18
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Elsevier
17 publications, 36.96%
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Wiley
5 publications, 10.87%
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Springer Nature
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Copernicus
1 publication, 2.17%
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The Chemical Society of Japan
1 publication, 2.17%
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IOP Publishing
1 publication, 2.17%
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Royal Society of Chemistry (RSC)
1 publication, 2.17%
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Trans Tech Publications
1 publication, 2.17%
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American Geophysical Union
1 publication, 2.17%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 2.17%
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2
4
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10
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14
16
18
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Chandrasekaran K., Thomas J. K., Thomas J. W. Photochemical reduction of carbonate to formaldehyde on TiO2 powder // Chemical Physics Letters. 1983. Vol. 99. No. 1. pp. 7-10.
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Chandrasekaran K., Thomas J. K., Thomas J. W. Photochemical reduction of carbonate to formaldehyde on TiO2 powder // Chemical Physics Letters. 1983. Vol. 99. No. 1. pp. 7-10.
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TY - JOUR
DO - 10.1016/0009-2614(83)80259-0
UR - https://doi.org/10.1016/0009-2614(83)80259-0
TI - Photochemical reduction of carbonate to formaldehyde on TiO2 powder
T2 - Chemical Physics Letters
AU - Chandrasekaran, K.
AU - Thomas, J K
AU - Thomas, J. William
PY - 1983
DA - 1983/07/01 00:00:00
PB - Elsevier
SP - 7-10
IS - 1
VL - 99
SN - 0009-2614
ER -
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@article{1983_Chandrasekaran,
author = {K. Chandrasekaran and J K Thomas and J. William Thomas},
title = {Photochemical reduction of carbonate to formaldehyde on TiO2 powder},
journal = {Chemical Physics Letters},
year = {1983},
volume = {99},
publisher = {Elsevier},
month = {jul},
url = {https://doi.org/10.1016/0009-2614(83)80259-0},
number = {1},
pages = {7--10},
doi = {10.1016/0009-2614(83)80259-0}
}
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Chandrasekaran, K., et al. “Photochemical reduction of carbonate to formaldehyde on TiO2 powder.” Chemical Physics Letters, vol. 99, no. 1, Jul. 1983, pp. 7-10. https://doi.org/10.1016/0009-2614(83)80259-0.