Elsevier
Chemical Physics Letters
,  том 168 ,  издание 3-4 ,  страницы 361-364

Kinetics of electron transfer between metal hexacyanide complexes

Тип публикации: Journal Article
Дата публикации: 1990-05-01
Elsevier
scimago Q2
wos Q2
БС2
SJR: 0.546
CiteScore: 5.9
Impact factor: 3.1
ISSN: 00092614, 18734448
Physical and Theoretical Chemistry
General Physics and Astronomy
Краткое описание
The electron transfer reactions between three isomorphic hexacyanides complexes, Fe(CN)63-4-, Os(CN)63-4- and Ru(CN)63-4- have been studied using the method of photoexcitation. The electron transfer rate constants between any two complexes increase by about a factor of 60 as the ionic strength is increased from 30 to 440 mM. An ionic-strength-independent reorganization energy of 1.1 eV was found for the hexacyanide self-exchange reaction when the data were analyzed according to the theory of Marcus.
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Cho K., Cham P. M., Che C. M. Kinetics of electron transfer between metal hexacyanide complexes // Chemical Physics Letters. 1990. Vol. 168. No. 3-4. pp. 361-364.
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Cho K., Cham P. M., Che C. M. Kinetics of electron transfer between metal hexacyanide complexes // Chemical Physics Letters. 1990. Vol. 168. No. 3-4. pp. 361-364.
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TY - JOUR
DO - 10.1016/0009-2614(90)85625-m
UR - https://doi.org/10.1016/0009-2614(90)85625-m
TI - Kinetics of electron transfer between metal hexacyanide complexes
T2 - Chemical Physics Letters
AU - Cho, K.-C.
AU - Cham, P M
AU - Che, Chi Ming
PY - 1990
DA - 1990/05/01
PB - Elsevier
SP - 361-364
IS - 3-4
VL - 168
SN - 0009-2614
SN - 1873-4448
ER -
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@article{1990_Cho,
author = {K.-C. Cho and P M Cham and Chi Ming Che},
title = {Kinetics of electron transfer between metal hexacyanide complexes},
journal = {Chemical Physics Letters},
year = {1990},
volume = {168},
publisher = {Elsevier},
month = {may},
url = {https://doi.org/10.1016/0009-2614(90)85625-m},
number = {3-4},
pages = {361--364},
doi = {10.1016/0009-2614(90)85625-m}
}
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Cho, K.-C., et al. “Kinetics of electron transfer between metal hexacyanide complexes.” Chemical Physics Letters, vol. 168, no. 3-4, May. 1990, pp. 361-364. https://doi.org/10.1016/0009-2614(90)85625-m.