Oxydation anodique de quelques N-arylhydroxylamines et proprietes electrochimiques des radicaux nitroxydes en milieu acetonitrile
1
Laboratoire d'Electrochimie Organique et Analytique, Département de Recherche Fondamentale, Centre d'Etudes Nucléaires de Grenoble, BP no. 85, Centre de tri 38041, Grenoble Cedex, France
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Publication type: Journal Article
Publication date: 1975-06-01
scimago Q1
wos Q1
SJR: 1.106
CiteScore: 10.6
Impact factor: 5.6
ISSN: 00134686, 18733859
General Chemical Engineering
Electrochemistry
Abstract
Resume Les proprietes electrochimiques du di p -anisylnitroxyde et de deux radicaux piperidiniques en milieu acetonitrile ont ete examinees a l'aide de la voltamperometrie a des electrodes a disque de platine poli et de carbone vitreux, de la voltammetrie cyclique et de la coulometrie a potentiel contrǒle. Les processus cathodiques dependent de la teneur du milieu en donneurs de protons et la reaction d'oxydation conduit a des ions oxoammonium stables. Les hydroxylamines aromatiques donnent deux vagues anodiques avec des intensites due courant limite dependant de la basicite du compose etudie. En milieu basique, l'electrolyse a potentiel contrǒle au niveau de la premiere vague necessite un electron par molecule oxydee et represente la meilleure methode de preparation electrohimique des radicaux nitroxydes. Les spectres d'absorption et de RPE sont egalement donnes.
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30
Total citations:
30
Citations from 2025:
1
(3.33%)
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MLA
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GOST
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Serve D. Oxydation anodique de quelques N-arylhydroxylamines et proprietes electrochimiques des radicaux nitroxydes en milieu acetonitrile // Electrochimica Acta. 1975. Vol. 20. No. 6-7. pp. 469-477.
GOST all authors (up to 50)
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Serve D. Oxydation anodique de quelques N-arylhydroxylamines et proprietes electrochimiques des radicaux nitroxydes en milieu acetonitrile // Electrochimica Acta. 1975. Vol. 20. No. 6-7. pp. 469-477.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/0013-4686(75)90036-5
UR - https://doi.org/10.1016/0013-4686(75)90036-5
TI - Oxydation anodique de quelques N-arylhydroxylamines et proprietes electrochimiques des radicaux nitroxydes en milieu acetonitrile
T2 - Electrochimica Acta
AU - Serve, D
PY - 1975
DA - 1975/06/01
PB - Elsevier
SP - 469-477
IS - 6-7
VL - 20
SN - 0013-4686
SN - 1873-3859
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1975_Serve,
author = {D Serve},
title = {Oxydation anodique de quelques N-arylhydroxylamines et proprietes electrochimiques des radicaux nitroxydes en milieu acetonitrile},
journal = {Electrochimica Acta},
year = {1975},
volume = {20},
publisher = {Elsevier},
month = {jun},
url = {https://doi.org/10.1016/0013-4686(75)90036-5},
number = {6-7},
pages = {469--477},
doi = {10.1016/0013-4686(75)90036-5}
}
Cite this
MLA
Copy
Serve, D.. “Oxydation anodique de quelques N-arylhydroxylamines et proprietes electrochimiques des radicaux nitroxydes en milieu acetonitrile.” Electrochimica Acta, vol. 20, no. 6-7, Jun. 1975, pp. 469-477. https://doi.org/10.1016/0013-4686(75)90036-5.