volume 98 issue 2 pages 502-512

Characterization of palladium surfaces with (+)-apopinene: Correlation of reaction paths with surface features

G. Smith
Publication typeJournal Article
Publication date1986-04-01
scimago Q1
wos Q1
SJR1.558
CiteScore10.9
Impact factor6.5
ISSN00219517, 10902694
Catalysis
Physical and Theoretical Chemistry
Abstract
The molecular probe (+)-apopinene is chosen for the characterization of metal surface sites because of its unique structural features. These features allow clear distinctions of adsorption side and double bond position. By measuring the relative rates of double bond migration and addition, k i k a , it is shown that (+)-apopinene is sensitive to 17 different Pd catalyst preparations. Among these, a set of alumina-supported Pd catalysts ranging in dispersions from 0.055 to 1.00 (131 to 8.4 A by EM) yielded results consistent with the notions that 3M-type sites (highly coordinatively unsaturated) catalyze principally addition and 2M-type sites catalyze principally isomerization. (+)-apopinene distinguishes between reduced PdO2 samples which have undergone different extents of Surface reconstruction.
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GOST |
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GOST Copy
Smith G. Characterization of palladium surfaces with (+)-apopinene: Correlation of reaction paths with surface features // Journal of Catalysis. 1986. Vol. 98. No. 2. pp. 502-512.
GOST all authors (up to 50) Copy
Smith G. Characterization of palladium surfaces with (+)-apopinene: Correlation of reaction paths with surface features // Journal of Catalysis. 1986. Vol. 98. No. 2. pp. 502-512.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/0021-9517(86)90338-6
UR - https://doi.org/10.1016/0021-9517(86)90338-6
TI - Characterization of palladium surfaces with (+)-apopinene: Correlation of reaction paths with surface features
T2 - Journal of Catalysis
AU - Smith, G.
PY - 1986
DA - 1986/04/01
PB - Elsevier
SP - 502-512
IS - 2
VL - 98
SN - 0021-9517
SN - 1090-2694
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{1986_Smith,
author = {G. Smith},
title = {Characterization of palladium surfaces with (+)-apopinene: Correlation of reaction paths with surface features},
journal = {Journal of Catalysis},
year = {1986},
volume = {98},
publisher = {Elsevier},
month = {apr},
url = {https://doi.org/10.1016/0021-9517(86)90338-6},
number = {2},
pages = {502--512},
doi = {10.1016/0021-9517(86)90338-6}
}
MLA
Cite this
MLA Copy
Smith, G.. “Characterization of palladium surfaces with (+)-apopinene: Correlation of reaction paths with surface features.” Journal of Catalysis, vol. 98, no. 2, Apr. 1986, pp. 502-512. https://doi.org/10.1016/0021-9517(86)90338-6.