Solubility of hydrogen in small particles of palladium
Publication type: Journal Article
Publication date: 1975-07-01
scimago Q1
wos Q1
SJR: 1.558
CiteScore: 10.9
Impact factor: 6.5
ISSN: 00219517, 10902694
Catalysis
Physical and Theoretical Chemistry
Abstract
The solubility of hydrogen in palladium, m , defined as the number of dissolved hydrogen atoms divided by the total number of metal atoms has been measured between 273 and 343 K from 13.3 to 53.3 kPa. At a given temperature and pressure, m was found to decrease linearly as the percentage dispersion D of the metal increased, m being zero at D = 100%. Measurements of m were carried out under conditions such that the surface of the metal particles was covered with almost a monolayer of hydrogen. This chemisorbed hydrogen seems to affect solubility of hydrogen in bulk palladium in a way similar to that of silver in palladium-silver alloys. Values of m are potentially helpful in the characterization of used palladium catalysts.
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Metrics
196
Total citations:
196
Citations from 2025:
4
(2.04%)
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MLA
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GOST
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Boudart M. Solubility of hydrogen in small particles of palladium // Journal of Catalysis. 1975. Vol. 39. No. 1. pp. 44-52.
GOST all authors (up to 50)
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Boudart M. Solubility of hydrogen in small particles of palladium // Journal of Catalysis. 1975. Vol. 39. No. 1. pp. 44-52.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/0021-9517(75)90280-8
UR - https://doi.org/10.1016/0021-9517(75)90280-8
TI - Solubility of hydrogen in small particles of palladium
T2 - Journal of Catalysis
AU - Boudart, M.
PY - 1975
DA - 1975/07/01
PB - Elsevier
SP - 44-52
IS - 1
VL - 39
SN - 0021-9517
SN - 1090-2694
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1975_Boudart,
author = {M. Boudart},
title = {Solubility of hydrogen in small particles of palladium},
journal = {Journal of Catalysis},
year = {1975},
volume = {39},
publisher = {Elsevier},
month = {jul},
url = {https://doi.org/10.1016/0021-9517(75)90280-8},
number = {1},
pages = {44--52},
doi = {10.1016/0021-9517(75)90280-8}
}
Cite this
MLA
Copy
Boudart, M.. “Solubility of hydrogen in small particles of palladium.” Journal of Catalysis, vol. 39, no. 1, Jul. 1975, pp. 44-52. https://doi.org/10.1016/0021-9517(75)90280-8.