Thermodynamic properties of palladium + indium alloys: solid electrolyte cell and differential scanning calorimetry studies
Publication type: Journal Article
Publication date: 1975-06-01
scimago Q2
wos Q2
SJR: 0.470
CiteScore: 5.5
Impact factor: 2.2
ISSN: 00219614, 10963626
Physical and Theoretical Chemistry
Atomic and Molecular Physics, and Optics
General Materials Science
Abstract
(ZrO 2 + CaO)|(Pd + In)|In 2 O 3 have been used to determine the thermodynamic activities and Gibbs free energies of formation of the α (f.c.c.)-solid-solution and intermediate phases Pd 3 In, Pd 2 In, Pd 5 In 3 , PdIn, Pd 2 In 3 , and PdIn 3 at 873 K. Values obtained have been combined with previous calorimetric measurements of their enthalpies of formation to yield integral entropies of formation. Specific heat capacities of the phases Pd 3 In, Pd 2 In, PdIn, and Pd 2 In 3 at 150, 200, and and 298 K have been obtained by differential scanning calorimetry. The system is characterized by marked negative deviations from Raoult's law and negative entropies of formation of the solid phases. An analysis of the latter into configurational, electronic, vibrational, and magnetic contributions is suggested. The defect structure of the CsCl-like compound PdIn is discussed in the light of the observed variation of thermodynamic properties across this phase.
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Bird J. M., Bryant A. W., Pratt J. N. Thermodynamic properties of palladium + indium alloys: solid electrolyte cell and differential scanning calorimetry studies // Journal of Chemical Thermodynamics. 1975. Vol. 7. No. 6. pp. 577-586.
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Bird J. M., Bryant A. W., Pratt J. N. Thermodynamic properties of palladium + indium alloys: solid electrolyte cell and differential scanning calorimetry studies // Journal of Chemical Thermodynamics. 1975. Vol. 7. No. 6. pp. 577-586.
Cite this
RIS
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TY - JOUR
DO - 10.1016/0021-9614(75)90192-5
UR - https://doi.org/10.1016/0021-9614(75)90192-5
TI - Thermodynamic properties of palladium + indium alloys: solid electrolyte cell and differential scanning calorimetry studies
T2 - Journal of Chemical Thermodynamics
AU - Bird, J. M.
AU - Bryant, A W
AU - Pratt, J. N.
PY - 1975
DA - 1975/06/01
PB - Elsevier
SP - 577-586
IS - 6
VL - 7
SN - 0021-9614
SN - 1096-3626
ER -
Cite this
BibTex (up to 50 authors)
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@article{1975_Bird,
author = {J. M. Bird and A W Bryant and J. N. Pratt},
title = {Thermodynamic properties of palladium + indium alloys: solid electrolyte cell and differential scanning calorimetry studies},
journal = {Journal of Chemical Thermodynamics},
year = {1975},
volume = {7},
publisher = {Elsevier},
month = {jun},
url = {https://doi.org/10.1016/0021-9614(75)90192-5},
number = {6},
pages = {577--586},
doi = {10.1016/0021-9614(75)90192-5}
}
Cite this
MLA
Copy
Bird, J. M., et al. “Thermodynamic properties of palladium + indium alloys: solid electrolyte cell and differential scanning calorimetry studies.” Journal of Chemical Thermodynamics, vol. 7, no. 6, Jun. 1975, pp. 577-586. https://doi.org/10.1016/0021-9614(75)90192-5.