The surface chemistry of hydrous manganese dioxide
Тип публикации: Journal Article
Дата публикации: 1974-03-01
scimago Q1
wos Q1
БС1
SJR: 1.885
CiteScore: 18.5
Impact factor: 9.7
ISSN: 00219797, 10957103
Surfaces, Coatings and Films
Electronic, Optical and Magnetic Materials
Colloid and Surface Chemistry
Biomaterials
Краткое описание
An experimental investigation has shown that H + and OH − are potential determining ions for the δMnO 2 surface. The pH (ZPC) was determined using electrophoretic mobilities and Na + and K + adsorption and found to be 2.25. Alkalimetric titration curves failed to provide a direct determination of the pH (ZPC), however, when combined with the Na + adsorption data they provide a means for estimating the surface charge. Surface charge values of approximately 100 μ C/cm 2 were found at pH 8, considerably higher than the charge on SiO 2 which has a similar pH (ZPC). Below pH 3.5 manganese was released to solution and the experimental data suggest that this is due to the reduction of MnO 2 . δMnO 2 is thermodynamically unstable with respect to H 2 O below that pH.
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stuart Murray J. The surface chemistry of hydrous manganese dioxide // Journal of Colloid and Interface Science. 1974. Vol. 46. No. 3. pp. 357-371.
ГОСТ со всеми авторами (до 50)
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stuart Murray J. The surface chemistry of hydrous manganese dioxide // Journal of Colloid and Interface Science. 1974. Vol. 46. No. 3. pp. 357-371.
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TY - JOUR
DO - 10.1016/0021-9797(74)90045-9
UR - https://doi.org/10.1016/0021-9797(74)90045-9
TI - The surface chemistry of hydrous manganese dioxide
T2 - Journal of Colloid and Interface Science
AU - stuart Murray, James
PY - 1974
DA - 1974/03/01
PB - Elsevier
SP - 357-371
IS - 3
VL - 46
SN - 0021-9797
SN - 1095-7103
ER -
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@article{1974_stuart Murray,
author = {James stuart Murray},
title = {The surface chemistry of hydrous manganese dioxide},
journal = {Journal of Colloid and Interface Science},
year = {1974},
volume = {46},
publisher = {Elsevier},
month = {mar},
url = {https://doi.org/10.1016/0021-9797(74)90045-9},
number = {3},
pages = {357--371},
doi = {10.1016/0021-9797(74)90045-9}
}
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MLA
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stuart Murray, James. “The surface chemistry of hydrous manganese dioxide.” Journal of Colloid and Interface Science, vol. 46, no. 3, Mar. 1974, pp. 357-371. https://doi.org/10.1016/0021-9797(74)90045-9.