An electron diffraction study of 3-methyldiaziridine and 1,2-dimethyldiaziridine
Publication type: Journal Article
Publication date: 1976-05-01
scimago Q2
wos Q2
SJR: 0.628
CiteScore: 8.0
Impact factor: 4.7
ISSN: 00222860, 18728014
Organic Chemistry
Inorganic Chemistry
Spectroscopy
Analytical Chemistry
Abstract
The structures of the title compounds, diaziridines, (the first to be studied in the gas phase) have been determined by electron diffraction. The following principal structural parameters were obtained with the estimated standard deviations parenthesized: 3-methyldiaziridine, N-C = 1.489(9) A, N-N = 1.444(13) A, C-C = 1.505(16) A, C-H = 1.107(5) A, α =∠ (C-C, NCN) = 61.3° (0.9); 1,2-dimethyldiaziridine, (parameters of the cycle CN 2 were assumed from the previous molecule), N-C (methyl) = 1.445(3) A, C-H = 1.108(9) A, ∠ C-N-Me = 112.0° (0.5), the two methyl groups are in the trans position. Vibrational amplitudes were also determined for all important distances.
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Mastryukov V. S. et al. An electron diffraction study of 3-methyldiaziridine and 1,2-dimethyldiaziridine // Journal of Molecular Structure. 1976. Vol. 32. No. 1. pp. 161-172.
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Mastryukov V. S., Dorofeeva O. V., Vilkov L. V., Golubinskii A. An electron diffraction study of 3-methyldiaziridine and 1,2-dimethyldiaziridine // Journal of Molecular Structure. 1976. Vol. 32. No. 1. pp. 161-172.
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RIS
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TY - JOUR
DO - 10.1016/0022-2860(76)80057-9
UR - https://doi.org/10.1016/0022-2860(76)80057-9
TI - An electron diffraction study of 3-methyldiaziridine and 1,2-dimethyldiaziridine
T2 - Journal of Molecular Structure
AU - Mastryukov, V S
AU - Dorofeeva, Olga V
AU - Vilkov, L. V.
AU - Golubinskii, A.V.
PY - 1976
DA - 1976/05/01
PB - Elsevier
SP - 161-172
IS - 1
VL - 32
SN - 0022-2860
SN - 1872-8014
ER -
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BibTex (up to 50 authors)
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@article{1976_Mastryukov,
author = {V S Mastryukov and Olga V Dorofeeva and L. V. Vilkov and A.V. Golubinskii},
title = {An electron diffraction study of 3-methyldiaziridine and 1,2-dimethyldiaziridine},
journal = {Journal of Molecular Structure},
year = {1976},
volume = {32},
publisher = {Elsevier},
month = {may},
url = {https://doi.org/10.1016/0022-2860(76)80057-9},
number = {1},
pages = {161--172},
doi = {10.1016/0022-2860(76)80057-9}
}
Cite this
MLA
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Mastryukov, V. S., et al. “An electron diffraction study of 3-methyldiaziridine and 1,2-dimethyldiaziridine.” Journal of Molecular Structure, vol. 32, no. 1, May. 1976, pp. 161-172. https://doi.org/10.1016/0022-2860(76)80057-9.