Is electrophilic substitution possible in the coordinated cyclopentadienyl ligand of early transition metal metallocene complexes? Molecular structure of binuclear nitrene niobocene complex [(C5 H4 C(COOEt)=N-μ-N)-(C5 H5 ) Nb]2
Тип публикации: Journal Article
Дата публикации: 1994-11-01
scimago Q3
wos Q2
БС2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
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Abstract Diazoacetates N 2 CHCOOR ( a : R = Et; b : R = t -Bu) readily react with Cp 2 NbH 3 to give CP 2 NbH(η 1 -N 2 CHCOOR) ( 1 ) as the first identifiable product, characterized by means of 1 H NMR spectroscope. Complex 1a converts stepwise into a unique binuclear nitrene niobocene complex [(C 5 H 4 -C(COOEt)=N-μ-N)C 5 H 5 )Nb] 2 ( 2a ). The latter is in fact a product of the Cp-ligand functionalized by the diazoacetate group. Mechanistic aspects of the formation of 2a are discussed with the results of an X-ray diffraction study.
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Nikonov G. I. et al. Is electrophilic substitution possible in the coordinated cyclopentadienyl ligand of early transition metal metallocene complexes? Molecular structure of binuclear nitrene niobocene complex [(C5H4C(COOEt)=N-μ-N)-(C5H5) Nb]2 // Journal of Organometallic Chemistry. 1994. Vol. 482. No. 1-2. pp. 187-190.
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Nikonov G. I., Putala M., Kazennova N. B., Lemenovskii D. A., Batsanov A. S., Struchkov Y. T. Is electrophilic substitution possible in the coordinated cyclopentadienyl ligand of early transition metal metallocene complexes? Molecular structure of binuclear nitrene niobocene complex [(C5H4C(COOEt)=N-μ-N)-(C5H5) Nb]2 // Journal of Organometallic Chemistry. 1994. Vol. 482. No. 1-2. pp. 187-190.
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TY - JOUR
DO - 10.1016/0022-328X(94)88200-2
UR - https://linkinghub.elsevier.com/retrieve/pii/0022328X94882002
TI - Is electrophilic substitution possible in the coordinated cyclopentadienyl ligand of early transition metal metallocene complexes? Molecular structure of binuclear nitrene niobocene complex [(C5H4C(COOEt)=N-μ-N)-(C5H5) Nb]2
T2 - Journal of Organometallic Chemistry
AU - Nikonov, G. I.
AU - Putala, Martin
AU - Kazennova, N B
AU - Lemenovskii, D A
AU - Batsanov, A. S.
AU - Struchkov, Yu. T.
PY - 1994
DA - 1994/11/01
PB - Elsevier
SP - 187-190
IS - 1-2
VL - 482
SN - 0022-328X
SN - 1872-8561
ER -
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@article{1994_Nikonov,
author = {G. I. Nikonov and Martin Putala and N B Kazennova and D A Lemenovskii and A. S. Batsanov and Yu. T. Struchkov},
title = {Is electrophilic substitution possible in the coordinated cyclopentadienyl ligand of early transition metal metallocene complexes? Molecular structure of binuclear nitrene niobocene complex [(C5H4C(COOEt)=N-μ-N)-(C5H5) Nb]2},
journal = {Journal of Organometallic Chemistry},
year = {1994},
volume = {482},
publisher = {Elsevier},
month = {nov},
url = {https://linkinghub.elsevier.com/retrieve/pii/0022328X94882002},
number = {1-2},
pages = {187--190},
doi = {10.1016/0022-328X(94)88200-2}
}
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Nikonov, G. I., et al. “Is electrophilic substitution possible in the coordinated cyclopentadienyl ligand of early transition metal metallocene complexes? Molecular structure of binuclear nitrene niobocene complex [(C5H4C(COOEt)=N-μ-N)-(C5H5) Nb]2.” Journal of Organometallic Chemistry, vol. 482, no. 1-2, Nov. 1994, pp. 187-190. https://linkinghub.elsevier.com/retrieve/pii/0022328X94882002.
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