Unusual reactivity of tritylcyclopentadienylmetal derivatives. Molecular structure of Ph3 CC5 H4 SnMe3 and Ph3 CC5 H4 TiCl3
Publication type: Journal Article
Publication date: 1995-08-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The preparative synthetic routes to tritylcyclopentadienyl metal derivatives of sodium, tin and titanium have been studied. Molecular structures of Ph3CC5H4SnMe3 (3) and Ph3CC5H4TiCl3 (4) have been defined. The ClPh agostic interaction in the structure of 4 provides an unprecedented low reactivity of 4 to nucleophiles of different natures.
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GOST
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Rufanov K. A. et al. Unusual reactivity of tritylcyclopentadienylmetal derivatives. Molecular structure of Ph3CC5H4SnMe3 and Ph3CC5H4TiCl3 // Journal of Organometallic Chemistry. 1995. Vol. 498. No. 1. pp. 37-39.
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Rufanov K. A., Churakov A. V., Kazennova N. B., Brusova G. P., Lemenovskii D. A., Kuzmina L. G. Unusual reactivity of tritylcyclopentadienylmetal derivatives. Molecular structure of Ph3CC5H4SnMe3 and Ph3CC5H4TiCl3 // Journal of Organometallic Chemistry. 1995. Vol. 498. No. 1. pp. 37-39.
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RIS
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TY - JOUR
DO - 10.1016/0022-328X(95)05449-Y
UR - https://linkinghub.elsevier.com/retrieve/pii/0022328X9505449Y
TI - Unusual reactivity of tritylcyclopentadienylmetal derivatives. Molecular structure of Ph3CC5H4SnMe3 and Ph3CC5H4TiCl3
T2 - Journal of Organometallic Chemistry
AU - Rufanov, Konstantin A.
AU - Churakov, Andrew V
AU - Kazennova, Nadezhda B
AU - Brusova, Galina P
AU - Lemenovskii, Dmitry A
AU - Kuzmina, Ludmila G
PY - 1995
DA - 1995/08/01
PB - Elsevier
SP - 37-39
IS - 1
VL - 498
SN - 0022-328X
SN - 1872-8561
ER -
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@article{1995_Rufanov,
author = {Konstantin A. Rufanov and Andrew V Churakov and Nadezhda B Kazennova and Galina P Brusova and Dmitry A Lemenovskii and Ludmila G Kuzmina},
title = {Unusual reactivity of tritylcyclopentadienylmetal derivatives. Molecular structure of Ph3CC5H4SnMe3 and Ph3CC5H4TiCl3},
journal = {Journal of Organometallic Chemistry},
year = {1995},
volume = {498},
publisher = {Elsevier},
month = {aug},
url = {https://linkinghub.elsevier.com/retrieve/pii/0022328X9505449Y},
number = {1},
pages = {37--39},
doi = {10.1016/0022-328X(95)05449-Y}
}
Cite this
MLA
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Rufanov, Konstantin A., et al. “Unusual reactivity of tritylcyclopentadienylmetal derivatives. Molecular structure of Ph3CC5H4SnMe3 and Ph3CC5H4TiCl3.” Journal of Organometallic Chemistry, vol. 498, no. 1, Aug. 1995, pp. 37-39. https://linkinghub.elsevier.com/retrieve/pii/0022328X9505449Y.