Journal of Organometallic Chemistry, volume 266, issue 2, pages 203-224

Nickel(0)-induzierte CC-verknüpfung zwischen kohlendioxid und alkinen sowie alkenen

Publication typeJournal Article
Publication date1984-05-01
Quartile SCImago
Q3
Quartile WOS
Q2
Impact factor2.3
ISSN0022328X
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
CO 2 and alkynes or alkenes undergo a 1/1 coupling in the presence of (Lig)Ni 0 complexes to give five-membered cyclic nickela complexes of types V and XVII. The influence of temperature and of the ligands upon the regioselectivity of the CC coupling in the case of monosubstituted olefins is reported, and the significance of these ring systems in preparative chemistry is emphasized. Oxanickelacyclopentenones (V) react with alkynes to form oxanickelacycloheptadienones (XIII). The structure of one of the compounds of this class has been determined by X-ray crystallography. Special features of these novel compounds, which can be readily prepared from CO 2 , are discussed together with the probable reaction mechanisms.

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GOST |
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GOST Copy
Hoberg H. et al. Nickel(0)-induzierte CC-verknüpfung zwischen kohlendioxid und alkinen sowie alkenen // Journal of Organometallic Chemistry. 1984. Vol. 266. No. 2. pp. 203-224.
GOST all authors (up to 50) Copy
Hoberg H., Schaefer D., Burkhart G., Krüger C., Romão M. J., Romão M. J. Nickel(0)-induzierte CC-verknüpfung zwischen kohlendioxid und alkinen sowie alkenen // Journal of Organometallic Chemistry. 1984. Vol. 266. No. 2. pp. 203-224.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1016/0022-328X(84)80129-1
UR - https://doi.org/10.1016/0022-328X(84)80129-1
TI - Nickel(0)-induzierte CC-verknüpfung zwischen kohlendioxid und alkinen sowie alkenen
T2 - Journal of Organometallic Chemistry
AU - Hoberg, H.
AU - Schaefer, D
AU - Burkhart, G.
AU - Krüger, C.
AU - Romão, M J
AU - Romão, M. J.
PY - 1984
DA - 1984/05/01
PB - Elsevier
SP - 203-224
IS - 2
VL - 266
SN - 0022-328X
ER -
BibTex |
Cite this
BibTex Copy
@article{1984_Hoberg,
author = {H. Hoberg and D Schaefer and G. Burkhart and C. Krüger and M J Romão and M. J. Romão},
title = {Nickel(0)-induzierte CC-verknüpfung zwischen kohlendioxid und alkinen sowie alkenen},
journal = {Journal of Organometallic Chemistry},
year = {1984},
volume = {266},
publisher = {Elsevier},
month = {may},
url = {https://doi.org/10.1016/0022-328X(84)80129-1},
number = {2},
pages = {203--224},
doi = {10.1016/0022-328X(84)80129-1}
}
MLA
Cite this
MLA Copy
Hoberg, H., et al. “Nickel(0)-induzierte CC-verknüpfung zwischen kohlendioxid und alkinen sowie alkenen.” Journal of Organometallic Chemistry, vol. 266, no. 2, May. 1984, pp. 203-224. https://doi.org/10.1016/0022-328X(84)80129-1.
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