Sulfone reagents in organic synthesis
Publication type: Journal Article
Publication date: 1985-04-01
scimago Q3
wos Q2
SJR: 0.385
CiteScore: 4.1
Impact factor: 2.4
ISSN: 0022328X, 18728561
Materials Chemistry
Organic Chemistry
Biochemistry
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The basic organometallic chemistry of β-silyl-substituted acetylenic, vinylic and alkyl sulfones has been investigated, with attention being given to metallation, carbometallation and the chemical reduction of carbon—carbon unsaturation. 2-Trimethylsilylvinyl and 2-trimethylsilylalkyl sulfones underwent smooth and stereoselective lithiation with RLi on the carbon α to the sulfonyl group. Carbometallation of vinyl sulfones could be achieved with RMgX or LiCuR2, but acetylenic sulfones carbometallated smoothly only with LiCuR2; with RMgX or RLi, these acetylenes underwent alkyldesulfonylation. The utility in synthesis of these metallo derivatives of sulfonyl-silyl-hydrocarbons is discussed and their value in elaborating carbon skeletons is illustrated for the preparation of alkenes, allenes, carbocycles and stereo-defined vinyl sulfones.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
1
2
3
4
5
6
7
|
|
|
Tetrahedron
7 publications, 11.86%
|
|
|
Journal of Organic Chemistry
4 publications, 6.78%
|
|
|
Tetrahedron Letters
4 publications, 6.78%
|
|
|
Chemistry - A European Journal
3 publications, 5.08%
|
|
|
Russian Chemical Reviews
2 publications, 3.39%
|
|
|
Journal of Organometallic Chemistry
2 publications, 3.39%
|
|
|
Angewandte Chemie
2 publications, 3.39%
|
|
|
Angewandte Chemie - International Edition
2 publications, 3.39%
|
|
|
Organic Letters
2 publications, 3.39%
|
|
|
Russian Journal of Organic Chemistry
2 publications, 3.39%
|
|
|
Beilstein Journal of Organic Chemistry
1 publication, 1.69%
|
|
|
Research on Chemical Intermediates
1 publication, 1.69%
|
|
|
Chemischer Informationsdienst
1 publication, 1.69%
|
|
|
Archiv der Pharmazie
1 publication, 1.69%
|
|
|
ChemistrySelect
1 publication, 1.69%
|
|
|
Medicinal Research Reviews
1 publication, 1.69%
|
|
|
Macromolecular Chemistry and Physics
1 publication, 1.69%
|
|
|
European Journal of Organic Chemistry
1 publication, 1.69%
|
|
|
Topics in Organometallic Chemistry
1 publication, 1.69%
|
|
|
Palladium in Heterocyclic Chemistry - A Guide for the Synthetic Chemist
1 publication, 1.69%
|
|
|
ChemSusChem
1 publication, 1.69%
|
|
|
1
2
3
4
5
6
7
|
Publishers
|
5
10
15
20
25
30
|
|
|
Elsevier
26 publications, 44.07%
|
|
|
Wiley
14 publications, 23.73%
|
|
|
American Chemical Society (ACS)
6 publications, 10.17%
|
|
|
Springer Nature
2 publications, 3.39%
|
|
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
2 publications, 3.39%
|
|
|
Pleiades Publishing
2 publications, 3.39%
|
|
|
Beilstein-Institut
1 publication, 1.69%
|
|
|
5
10
15
20
25
30
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
59
Total citations:
59
Citations from 2024:
2
(3%)
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Eisch J. J., Behrooz M., Dua S. K. Sulfone reagents in organic synthesis // Journal of Organometallic Chemistry. 1985. Vol. 285. No. 1-3. pp. 121-136.
GOST all authors (up to 50)
Copy
Eisch J. J., Behrooz M., Dua S. K. Sulfone reagents in organic synthesis // Journal of Organometallic Chemistry. 1985. Vol. 285. No. 1-3. pp. 121-136.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/0022-328X(85)87362-9
UR - https://doi.org/10.1016/0022-328X(85)87362-9
TI - Sulfone reagents in organic synthesis
T2 - Journal of Organometallic Chemistry
AU - Eisch, John J
AU - Behrooz, Mohammad
AU - Dua, Suresh K
PY - 1985
DA - 1985/04/01
PB - Elsevier
SP - 121-136
IS - 1-3
VL - 285
SN - 0022-328X
SN - 1872-8561
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1985_Eisch,
author = {John J Eisch and Mohammad Behrooz and Suresh K Dua},
title = {Sulfone reagents in organic synthesis},
journal = {Journal of Organometallic Chemistry},
year = {1985},
volume = {285},
publisher = {Elsevier},
month = {apr},
url = {https://doi.org/10.1016/0022-328X(85)87362-9},
number = {1-3},
pages = {121--136},
doi = {10.1016/0022-328X(85)87362-9}
}
Cite this
MLA
Copy
Eisch, John J., et al. “Sulfone reagents in organic synthesis.” Journal of Organometallic Chemistry, vol. 285, no. 1-3, Apr. 1985, pp. 121-136. https://doi.org/10.1016/0022-328X(85)87362-9.