Journal of Solid State Chemistry

, том 100 , издание 1 , страницы 30-36

NEW COMPLEX OXIDES IN R-BA-TH-CU-O SYSTEMS (R = LA-GD)

Тип публикации: Journal Article

Дата публикации: 1992-09-01

Elsevier

Journal of Solid State Chemistry

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SJR: 0.629

CiteScore: 6.8

Impact factor: 3.5

ISSN: 00224596, 1095726X

DOI: 10.1016/0022-4596(92)90153-M

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Materials Chemistry

Ceramics and Composites

Electronic, Optical and Magnetic Materials

Inorganic Chemistry

Physical and Theoretical Chemistry

Condensed Matter Physics

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Abstract The new complex oxides R2Ba1.33Th0.67Cu3O8+δ (R = La, Pr) and La0.67Ba1.33R2−xThxCu3O8+δ (R = NdGd, x = 0.5, 0.67) were synthesized. These compounds have a similar structure to the Ce-223 high-Tc oxides. The oxygen content (or δ) was varied over a wide range after annealing at high oxygen pressure (up to 90 atm). Unit cell parameters and δ values for all the new phases were determined. The resistivities of these semiconducting compounds obey the law ϱ = ϱoT−α. A single crystal of Nd2Ba1.5Th0.5Cu3−xAlxO8+δ (x = 0.3, δ = 0.8) was obtained and its structure was determined by X-ray single-crystal experiment (tetragonal system, space group I4 mmm , a = 3.9057(5) A, c = 28.569(4) A, Z = 2).

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Kopnin E. M. et al. NEW COMPLEX OXIDES IN R-BA-TH-CU-O SYSTEMS (R = LA-GD) // Journal of Solid State Chemistry. 1992. Vol. 100. No. 1. pp. 30-36.

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Kopnin E. M., Миронов А. С., Antipov E. V., Kovba L. M., Akselrud L. G., Muttik I. G., Moshchalkov V. NEW COMPLEX OXIDES IN R-BA-TH-CU-O SYSTEMS (R = LA-GD) // Journal of Solid State Chemistry. 1992. Vol. 100. No. 1. pp. 30-36.

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TY - JOUR

DO - 10.1016/0022-4596(92)90153-M

UR - https://linkinghub.elsevier.com/retrieve/pii/002245969290153M

TI - NEW COMPLEX OXIDES IN R-BA-TH-CU-O SYSTEMS (R = LA-GD)

T2 - Journal of Solid State Chemistry

AU - Kopnin, E. M.

AU - Миронов, А. С.

AU - Antipov, Evgeny V.

AU - Kovba, L. M.

AU - Akselrud, L. G.

AU - Muttik, I G

AU - Moshchalkov, V.

PY - 1992

DA - 1992/09/01

PB - Elsevier

SP - 30-36

IS - 1

VL - 100

SN - 0022-4596

SN - 1095-726X

ER -

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@article{1992_Kopnin,

author = {E. M. Kopnin and А. С. Миронов and Evgeny V. Antipov and L. M. Kovba and L. G. Akselrud and I G Muttik and V. Moshchalkov},

title = {NEW COMPLEX OXIDES IN R-BA-TH-CU-O SYSTEMS (R = LA-GD)},

journal = {Journal of Solid State Chemistry},

year = {1992},

volume = {100},

publisher = {Elsevier},

month = {sep},

url = {https://linkinghub.elsevier.com/retrieve/pii/002245969290153M},

number = {1},

pages = {30--36},

doi = {10.1016/0022-4596(92)90153-M}

}

MLA

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Kopnin, E. M., et al. “NEW COMPLEX OXIDES IN R-BA-TH-CU-O SYSTEMS (R = LA-GD).” Journal of Solid State Chemistry, vol. 100, no. 1, Sep. 1992, pp. 30-36. https://linkinghub.elsevier.com/retrieve/pii/002245969290153M.