The crystal structure of Eu2BaZnO5 and the optical and magnetic properties of some related oxides
1
Laboratoire de Physico-Chimie des Matériaux, Ecole Normale Supérieure de Takaddoum B.P. 5118, RabatMorocco
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Laboratoire de Chimie du Solide du CNRS, 351 Cours de La Libération, 33405 Talence CEDEX, France
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3
Laboratoire de Chimie du Solide Appliquée, Faculté des Sciences, Avenue Ibn Batouta, RabatMorocco
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Publication type: Journal Article
Publication date: 1991-05-01
General Engineering
Abstract
The structure of the Eu2BaZnO5 oxide has been solved for a single crystal. The orthorhombic cell parameters are a = 12.537(11) A , b = 5.791(8) A and c = 7.186(11) A . The space group is Pnma. In the refinement 1197 independent reflections (I>3σ(I)) have been used. The R factor value is 0.033 (Rw = 0.036). The europium ions occupy two different sites with seven oxygen bonds in the lattice. The Ba2+ ions are eleven-fold surrounded. The zinc ions are located in a distorted square-based pyramidal environment. An optical study of Er2BaZnO5 and the neodymium-doped Ln2BaZnO5 (Ln ≡ Er, Tm) has confirmed that the rare-earth atom occupies two sites in these compounds. Magnetic susceptibility measurements show the effect of the crystal field at low temperature.
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Taibi M. et al. The crystal structure of Eu2BaZnO5 and the optical and magnetic properties of some related oxides // Journal of the Less Common Metals. 1991. Vol. 169. No. 2. pp. 217-225.
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Taibi M., Aride J., Darriet J., Boukhari A. The crystal structure of Eu2BaZnO5 and the optical and magnetic properties of some related oxides // Journal of the Less Common Metals. 1991. Vol. 169. No. 2. pp. 217-225.
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TY - JOUR
DO - 10.1016/0022-5088(91)90070-k
UR - https://doi.org/10.1016/0022-5088(91)90070-k
TI - The crystal structure of Eu2BaZnO5 and the optical and magnetic properties of some related oxides
T2 - Journal of the Less Common Metals
AU - Taibi, M.
AU - Aride, J.
AU - Darriet, J.
AU - Boukhari, A.
PY - 1991
DA - 1991/05/01
PB - Elsevier
SP - 217-225
IS - 2
VL - 169
SN - 0022-5088
ER -
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@article{1991_Taibi,
author = {M. Taibi and J. Aride and J. Darriet and A. Boukhari},
title = {The crystal structure of Eu2BaZnO5 and the optical and magnetic properties of some related oxides},
journal = {Journal of the Less Common Metals},
year = {1991},
volume = {169},
publisher = {Elsevier},
month = {may},
url = {https://doi.org/10.1016/0022-5088(91)90070-k},
number = {2},
pages = {217--225},
doi = {10.1016/0022-5088(91)90070-k}
}
Cite this
MLA
Copy
Taibi, M., et al. “The crystal structure of Eu2BaZnO5 and the optical and magnetic properties of some related oxides.” Journal of the Less Common Metals, vol. 169, no. 2, May. 1991, pp. 217-225. https://doi.org/10.1016/0022-5088(91)90070-k.