Materials Research Bulletin, volume 15, issue 11, pages 1661-1667
New Li+ ion conductors in the system, Li4GeO4-Li3VO4
Publication type: Journal Article
Publication date: 1980-11-01
Journal:
Materials Research Bulletin
Quartile SCImago
Q1
Quartile WOS
Q2
Impact factor: 5.4
ISSN: 00255408
Condensed Matter Physics
General Materials Science
Mechanical Engineering
Mechanics of Materials
Abstract
New Li+ ion conducting solid electrolytes have been found in the system Li4GeO4-Li3VO4. Of the compositions studied, Li3.6Ge0.6V0.4O4 has the highest conductivity with σ ∼ 4 × 10−5 ohm−1cm−1 at 18°C rising to ∼ 10−2 ohm−1 cm−1 at 190°C. The activation energy is ∼0.44 eV. These conductivity values are among the highest yet found for Li+ ion conductors; the room temperature value is much higher than in LISICON, Li3.5Zn0.25GeO4, or in Li3.4Si0.4P0.6O4 and is comparable to that in LiI/A l 2 O 3 mixtures. These solid electrolytes are easy to synthesize, thermodynamically stable and insensitive to atmospheric attack. Structurally, they are solid solutions based on γII Li3VO4, a γ tetrahedral structure; high conductivity is due to the interstitial Li+ ions which are created during solid solution formation.
Top-30
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1 publication, 1.18%
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1 publication, 1.18%
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1 publication, 1.18%
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Citations by publishers
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5
10
15
20
25
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Elsevier
25 publications, 29.41%
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American Chemical Society (ACS)
15 publications, 17.65%
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Springer Nature
9 publications, 10.59%
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Wiley
8 publications, 9.41%
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3 publications, 3.53%
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The Electrochemical Society of Japan
2 publications, 2.35%
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The Electrochemical Society
2 publications, 2.35%
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Japan Institute of Metals and Materials
2 publications, 2.35%
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Royal Society of Chemistry (RSC)
2 publications, 2.35%
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Trans Tech Publications
2 publications, 2.35%
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American Physical Society (APS)
1 publication, 1.18%
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American Vacuum Society
1 publication, 1.18%
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IOP Publishing
1 publication, 1.18%
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Taylor & Francis
1 publication, 1.18%
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Walter de Gruyter
1 publication, 1.18%
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Ceramic Society of Japan
1 publication, 1.18%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 1.18%
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5
10
15
20
25
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Kuwano J., West A. J. New Li+ ion conductors in the system, Li4GeO4-Li3VO4 // Materials Research Bulletin. 1980. Vol. 15. No. 11. pp. 1661-1667.
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Kuwano J., West A. J. New Li+ ion conductors in the system, Li4GeO4-Li3VO4 // Materials Research Bulletin. 1980. Vol. 15. No. 11. pp. 1661-1667.
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TY - JOUR
DO - 10.1016/0025-5408(80)90249-4
UR - https://doi.org/10.1016/0025-5408(80)90249-4
TI - New Li+ ion conductors in the system, Li4GeO4-Li3VO4
T2 - Materials Research Bulletin
AU - Kuwano, J.
AU - West, A. Joshua
PY - 1980
DA - 1980/11/01 00:00:00
PB - Elsevier
SP - 1661-1667
IS - 11
VL - 15
SN - 0025-5408
ER -
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@article{1980_Kuwano,
author = {J. Kuwano and A. Joshua West},
title = {New Li+ ion conductors in the system, Li4GeO4-Li3VO4},
journal = {Materials Research Bulletin},
year = {1980},
volume = {15},
publisher = {Elsevier},
month = {nov},
url = {https://doi.org/10.1016/0025-5408(80)90249-4},
number = {11},
pages = {1661--1667},
doi = {10.1016/0025-5408(80)90249-4}
}
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Kuwano, J., and A. Joshua West. “New Li+ ion conductors in the system, Li4GeO4-Li3VO4.” Materials Research Bulletin, vol. 15, no. 11, Nov. 1980, pp. 1661-1667. https://doi.org/10.1016/0025-5408(80)90249-4.