Two oxygen states and the role of carbon in partial oxidation of ethylene over silver
Тип публикации: Journal Article
Дата публикации: 1990-06-01
scimago Q2
wos Q3
БС2
SJR: 0.419
CiteScore: 3.5
Impact factor: 1.8
ISSN: 00396028, 18792758
Materials Chemistry
Surfaces, Coatings and Films
Condensed Matter Physics
Surfaces and Interfaces
Краткое описание
The interaction of O 2 and a C 2 H 4 + O 2 reaction mixture with the surface of polycrystalline silver at P = 10 −2 −10 3 Pa and T = 420−620 K was studied by XPS, TDS and TPR. The formation of two states of O ads with E BO 1s = 528.4 and 530.5 eV is shown and the necessity of participation of both states in ethylene epoxidation is stated. It is assumed that an elementary carbon resulting from oxidative dehydrogenation of ethylene stabilizes defects of the silver surface and takes part in the formation of a mixed adsorption layer consisting of two states of O ads .
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Bukhtiyarov V., Boronin A., Savchenko V. Two oxygen states and the role of carbon in partial oxidation of ethylene over silver // Surface Science. 1990. Vol. 232. No. 1-2. p. L205-L209.
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Bukhtiyarov V., Boronin A., Savchenko V. Two oxygen states and the role of carbon in partial oxidation of ethylene over silver // Surface Science. 1990. Vol. 232. No. 1-2. p. L205-L209.
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TY - JOUR
DO - 10.1016/0039-6028(90)90580-2
UR - https://doi.org/10.1016/0039-6028(90)90580-2
TI - Two oxygen states and the role of carbon in partial oxidation of ethylene over silver
T2 - Surface Science
AU - Bukhtiyarov, Valerii
AU - Boronin, Andrei
AU - Savchenko, V.I
PY - 1990
DA - 1990/06/01
PB - Elsevier
SP - L205-L209
IS - 1-2
VL - 232
SN - 0039-6028
SN - 1879-2758
ER -
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BibTex (до 50 авторов)
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@article{1990_Bukhtiyarov,
author = {Valerii Bukhtiyarov and Andrei Boronin and V.I Savchenko},
title = {Two oxygen states and the role of carbon in partial oxidation of ethylene over silver},
journal = {Surface Science},
year = {1990},
volume = {232},
publisher = {Elsevier},
month = {jun},
url = {https://doi.org/10.1016/0039-6028(90)90580-2},
number = {1-2},
pages = {L205--L209},
doi = {10.1016/0039-6028(90)90580-2}
}
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MLA
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Bukhtiyarov, Valerii, et al. “Two oxygen states and the role of carbon in partial oxidation of ethylene over silver.” Surface Science, vol. 232, no. 1-2, Jun. 1990, pp. L205-L209. https://doi.org/10.1016/0039-6028(90)90580-2.