Tetrahedron Letters

, том 21 , издание 48 , страницы 4593-4596

Unusual regiochemistry in a beckmann-like rearrangement of camphor. α-Camphidone via methylene migration.

Тип публикации: Journal Article

Дата публикации: 1980-01-01

Elsevier

Tetrahedron Letters

SCImago Q3

WOS Q3

БС2

SJR: 0.285

CiteScore: 2.8

Impact factor: 1.4

ISSN: 00404039, 18733581

DOI: 10.1016/0040-4039(80)80082-7

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Organic Chemistry

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Краткое описание

Reaction of camphor with hydroxylamine-O-sulfonic acid affords the nitrogen insertion product α-camphidone by migration of the methylene group rather than the bridgehead. Since Beckmann rearrangements of trigonal oximes afford bridgehead cleavage products with camphor, an alternative synchronous rearrangement of a tetrahedral intermediate is proposed for this Beckmann-like reaction.

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Krow G. R., Szczepanski S. Unusual regiochemistry in a beckmann-like rearrangement of camphor. α-Camphidone via methylene migration. // Tetrahedron Letters. 1980. Vol. 21. No. 48. pp. 4593-4596.

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Krow G. R., Szczepanski S. Unusual regiochemistry in a beckmann-like rearrangement of camphor. α-Camphidone via methylene migration. // Tetrahedron Letters. 1980. Vol. 21. No. 48. pp. 4593-4596.

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TY - JOUR

DO - 10.1016/0040-4039(80)80082-7

UR - https://doi.org/10.1016/0040-4039(80)80082-7

TI - Unusual regiochemistry in a beckmann-like rearrangement of camphor. α-Camphidone via methylene migration.

T2 - Tetrahedron Letters

AU - Krow, Grant R

AU - Szczepanski, Steven

PY - 1980

DA - 1980/01/01

PB - Elsevier

SP - 4593-4596

IS - 48

VL - 21

SN - 0040-4039

SN - 1873-3581

ER -

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@article{1980_Krow,

author = {Grant R Krow and Steven Szczepanski},

title = {Unusual regiochemistry in a beckmann-like rearrangement of camphor. α-Camphidone via methylene migration.},

journal = {Tetrahedron Letters},

year = {1980},

volume = {21},

publisher = {Elsevier},

month = {jan},

url = {https://doi.org/10.1016/0040-4039(80)80082-7},

number = {48},

pages = {4593--4596},

doi = {10.1016/0040-4039(80)80082-7}

}

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MLA Скопировать

Krow, Grant R., and Steven Szczepanski. “Unusual regiochemistry in a beckmann-like rearrangement of camphor. α-Camphidone via methylene migration..” Tetrahedron Letters, vol. 21, no. 48, Jan. 1980, pp. 4593-4596. https://doi.org/10.1016/0040-4039(80)80082-7.

Издатель

Elsevier

Журнал

Tetrahedron Letters

SCImago Q3

WOS Q3

БС2

SJR

0.285

CiteScore

2.8

Impact factor

1.4

ISSN

00404039 (Print)

18733581 (Electronic)

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