Tetrahedron Letters

, volume 32 , issue 11 , pages 1483-1488

More efficient metallation of alkylbenzenes by modified superbases from butyllithium and potassium alkoxides. Effect of alkoxide structure and concentration

Lubomír Lochmann ¹

Jaromír Petránek ¹

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Ínstitute of Macromolecular Chemistry, Czechoslovak Academy of Sciences, 162 06 Prague 6 Czechoslovakia | |

Publication type: Journal Article

Publication date: 1991-03-01

Elsevier

Tetrahedron Letters

scimago Q3

wos Q3

SJR: 0.334

CiteScore: 3.2

Impact factor: 1.5

ISSN: 00404039, 18733581

DOI: 10.1016/0040-4039(91)80364-C

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Organic Chemistry

Drug Discovery

Biochemistry

Abstract

Higher yields and higher reaction rates, as well as more selective metallation in the side chain of alkylbenzenes are achieved by Superbases from alkyllithium compounds and potassium alkoxides which contain an enhanced of an alkoxide with a structure more bulky than that of tert-butoxide.

Found

1 citation

Ol'shevskaya Valentina

36 publications, 353 citations

h-index: 12

A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

1 citation

Anisimov Anton

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PhD in Chemistry

69 publications, 1 036 citations, 5 reviews

h-index: 19

A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

Moscow Institute of Physics and Technology

Tula State Pedagogical University named after L.N. Tolstoy

Research interests

"Smart" materials

Green chemistry

High molecular weight compounds

Organosilicon Chemistry

1 citation

Minyaylo Ekaterina

14 publications, 69 citations

h-index: 4

A.N.Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences

Research interests

Dendrimers

Organosilicon Compounds

Polyhedral carboranes

Polymer science

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Lochmann L., Petránek J. More efficient metallation of alkylbenzenes by modified superbases from butyllithium and potassium alkoxides. Effect of alkoxide structure and concentration // Tetrahedron Letters. 1991. Vol. 32. No. 11. pp. 1483-1488.

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RIS |

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RIS Copy

TY - JOUR

DO - 10.1016/0040-4039(91)80364-C

UR - https://doi.org/10.1016/0040-4039(91)80364-C

TI - More efficient metallation of alkylbenzenes by modified superbases from butyllithium and potassium alkoxides. Effect of alkoxide structure and concentration

T2 - Tetrahedron Letters

AU - Lochmann, Lubomír

AU - Petránek, Jaromír

PY - 1991

DA - 1991/03/01

PB - Elsevier

SP - 1483-1488

IS - 11

VL - 32

SN - 0040-4039

SN - 1873-3581

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{1991_Lochmann,

author = {Lubomír Lochmann and Jaromír Petránek},

title = {More efficient metallation of alkylbenzenes by modified superbases from butyllithium and potassium alkoxides. Effect of alkoxide structure and concentration},

journal = {Tetrahedron Letters},

year = {1991},

volume = {32},

publisher = {Elsevier},

month = {mar},

url = {https://doi.org/10.1016/0040-4039(91)80364-C},

number = {11},

pages = {1483--1488},

doi = {10.1016/0040-4039(91)80364-C}

}

MLA

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MLA Copy

Lochmann, Lubomír, and Jaromír Petránek. “More efficient metallation of alkylbenzenes by modified superbases from butyllithium and potassium alkoxides. Effect of alkoxide structure and concentration.” Tetrahedron Letters, vol. 32, no. 11, Mar. 1991, pp. 1483-1488. https://doi.org/10.1016/0040-4039(91)80364-C.

Publisher

Elsevier

Journal

Tetrahedron Letters

scimago Q3

wos Q3

SJR

0.334

CiteScore

3.2

Impact factor

1.5

ISSN

00404039 (Print)

18733581 (Electronic)