Thermochimica Acta, volume 105, pages 287-293
The relationship between ignition temperature and thermal stability for selected primary explosives
1
Materials Research Laboratories, P.O. Box 50, Ascot Vale, Victoria, 3032 Australia
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Publication type: Journal Article
Publication date: 1986-09-01
Journal:
Thermochimica Acta
Quartile SCImago
Q2
Quartile WOS
Q2
SJR: 0.572
CiteScore: 6.5
Impact factor: 3.1
ISSN: 00406031, 1872762X
Physical and Theoretical Chemistry
Condensed Matter Physics
Instrumentation
Abstract
Thermal stability of nine primary explosives has been determined at 89 °C. Half-lives (t 1 2 for thermal decomposition are correlated against temperature of ignition (TI) and the peak maxima (Tmax) in the DSC traces. A trend to increased thermal stability with increased TI and Tmax is observed, with Tmax giving the better correlation. Thermal decomposition of three of the materials is accompanied by a decrease in Tmax by up to 10 °C at 50% decomposition. This could be an indication of autocatalytic decomposition.
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Spear R. C., Maksacheff M. The relationship between ignition temperature and thermal stability for selected primary explosives // Thermochimica Acta. 1986. Vol. 105. pp. 287-293.
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Spear R. C., Maksacheff M. The relationship between ignition temperature and thermal stability for selected primary explosives // Thermochimica Acta. 1986. Vol. 105. pp. 287-293.
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TY - JOUR
DO - 10.1016/0040-6031(86)85245-5
UR - https://doi.org/10.1016/0040-6031(86)85245-5
TI - The relationship between ignition temperature and thermal stability for selected primary explosives
T2 - Thermochimica Acta
AU - Spear, Robert C.
AU - Maksacheff, Michael
PY - 1986
DA - 1986/09/01
PB - Elsevier
SP - 287-293
VL - 105
SN - 0040-6031
SN - 1872-762X
ER -
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@article{1986_Spear,
author = {Robert C. Spear and Michael Maksacheff},
title = {The relationship between ignition temperature and thermal stability for selected primary explosives},
journal = {Thermochimica Acta},
year = {1986},
volume = {105},
publisher = {Elsevier},
month = {sep},
url = {https://doi.org/10.1016/0040-6031(86)85245-5},
pages = {287--293},
doi = {10.1016/0040-6031(86)85245-5}
}