Polymer Degradation and Stability, volume 46, issue 2, pages 225-234

Thermal decomposition of tetrazole-containing polymers. IV: poly-1-vinyl-5-methyltetrazole and poly-1-vinyl-5-phenyltetrazole

S.V. Levchik ¹

Oleg A. Ivashkevich ¹

L. Costa ²

P.N. Gaponik ¹

T N Andreeva ¹

Hide authors affiliations Show authors affiliations: 2 affiliations

Research Institute for Physical Chemical Problems, Byelorussian State Universtiy, Leningradskaya, 14-220050 Minsk, Belarus |

Dipartimento di Chimica Inorganica, Chimica Fisica e Chimica dei Materiali, Universitá di Torino, Via P. Giuria 7,10125 Torino, Italy |

Publication type: Journal Article

Publication date: 1994-01-01

Elsevier

Journal: Polymer Degradation and Stability

Quartile SCImago

Quartile WOS

Impact factor: 5.9

ISSN: 01413910

DOI: 10.1016/0141-3910(94)90054-x

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Materials Chemistry

Condensed Matter Physics

Polymers and Plastics

Mechanics of Materials

Abstract

The thermal decomposition of poly-1-vinyl-5-methyltetrazole (P-1VMT) and poly-1-vinyl-5-phenyltetrazole (P-1VPT) was studied by high resolution thermogravimetry (HRTG) differential scanning calorimetry (DSC) and thermal volatilization analysis (TVA). Solid residues, high boiling products, and gases were collected at different stages of the thermal decomposition and identified by FTIR and/or GC-MS. Both P-1VMT and P-1VPT show complex multistep decomposition on progressive heating. The thermal decomposition starts from degradation of tetrazole pendant groups. At the beginning, P-1VMT presumably eliminates acetonitrile, whereas P-1VPT eliminates nitrogen. On further heating, the partially decomposed polymers melt and an evolution of the pendant groups (5-methyltetrazole and 5-phenyltetrazole) is observed. Thermal fragmentation of the polymeric chain occurs at high temperatures (≥320°C).

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Levchik S. et al. Thermal decomposition of tetrazole-containing polymers. IV: poly-1-vinyl-5-methyltetrazole and poly-1-vinyl-5-phenyltetrazole // Polymer Degradation and Stability. 1994. Vol. 46. No. 2. pp. 225-234.

GOST all authors (up to 50) Copy

Levchik S., Ivashkevich O. A., Costa L., Gaponik P., Andreeva T. N. Thermal decomposition of tetrazole-containing polymers. IV: poly-1-vinyl-5-methyltetrazole and poly-1-vinyl-5-phenyltetrazole // Polymer Degradation and Stability. 1994. Vol. 46. No. 2. pp. 225-234.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1016/0141-3910(94)90054-x

UR - https://doi.org/10.1016/0141-3910(94)90054-x

TI - Thermal decomposition of tetrazole-containing polymers. IV: poly-1-vinyl-5-methyltetrazole and poly-1-vinyl-5-phenyltetrazole

T2 - Polymer Degradation and Stability

AU - Levchik, S.V.

AU - Ivashkevich, Oleg A.

AU - Costa, L.

AU - Gaponik, P.N.

AU - Andreeva, T N

PY - 1994

DA - 1994/01/01 00:00:00

PB - Elsevier

SP - 225-234

IS - 2

VL - 46

SN - 0141-3910

ER -

BibTex |

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@article{1994_Levchik,

author = {S.V. Levchik and Oleg A. Ivashkevich and L. Costa and P.N. Gaponik and T N Andreeva},

title = {Thermal decomposition of tetrazole-containing polymers. IV: poly-1-vinyl-5-methyltetrazole and poly-1-vinyl-5-phenyltetrazole},

journal = {Polymer Degradation and Stability},

year = {1994},

volume = {46},

publisher = {Elsevier},

month = {jan},

url = {https://doi.org/10.1016/0141-3910(94)90054-x},

number = {2},

pages = {225--234},

doi = {10.1016/0141-3910(94)90054-x}

}

MLA

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MLA Copy

Levchik, S.V., et al. “Thermal decomposition of tetrazole-containing polymers. IV: poly-1-vinyl-5-methyltetrazole and poly-1-vinyl-5-phenyltetrazole.” Polymer Degradation and Stability, vol. 46, no. 2, Jan. 1994, pp. 225-234. https://doi.org/10.1016/0141-3910(94)90054-x.

Found error?

Publisher

Elsevier

Journal

Polymer Degradation and Stability

Quartile SCImago

Quartile WOS

Impact factor

5.9

ISSN

01413910 (Print)