Electrical properties of amorphous lithium electrolyte thin films

Тип публикации: Journal Article

Дата публикации: 1992-07-01

Elsevier

Solid State Ionics

SCImago Q2

WOS Q2

БС1

SJR: 0.643

CiteScore: 5.3

Impact factor: 3.3

ISSN: 01672738, 18727689

DOI: 10.1016/0167-2738(92)90442-R

Скопировать DOI

General Chemistry

Condensed Matter Physics

General Materials Science

Краткое описание

The impedance of xLi2O·ySiO2·zP2O5 thin films deposited by RF-magnetron sputtering was analyzed using two models in which the frequency dependence of the bulk response was represented by: (1) a Cole-Cole dielectric function and (2) a constant phase angle element. Increases in the conductivity with Li2O concentration and with addition of SiO2 to Li2O-P2O5 compositions are attributed to an increase in Li+ mobility caused by changes in the film structure. A new amorphous oxynitride electrolyte, Li3.3PO3.9N0.17, prepared by sputtering Li3PO4 in N2, has a conductivity at 25°C of 2×10−6S/cm and is stable in conta with lithium.

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