Enzymes as catalysts of electrochemical reactions
Publication type: Journal Article
Publication date: 1978-12-01
scimago Q4
SJR: 0.140
CiteScore: 1.2
Impact factor: —
ISSN: 10013555, 03045102
General Engineering
Abstract
The paper describes a theory for constructing electrocatalysts based on immobilized enzymes. High-rate enzymatic electron-transfer reactions in solutions and heterogeneous systems are analyzed. Macrokinetics of electrocatalysis with enzymes anchored to equiaccessible surface electrodes is discussed, and a number of expressions interrelating electrode potential and current output on the one hand, and kinetic and microkinetic characteristics of the system on the other, are derived. Electron transfer from the enzyme active center to the conducting matrix is discussed. Two mechanisms are considered: the direct electron transfer mechanism and the mechanism involving intermediate carriers (mediators). The technological potential of immobilized enzyme electrocatalysis is surveyed (bioelectrochemical converters, biophotolysis of water, specific electrosynthesis, biochemical sensors).
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Metrics
28
Total citations:
28
Citations from 2024:
1
(3.57%)
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MLA
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GOST
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Varfolomeev S. D., Berezin L. V. Enzymes as catalysts of electrochemical reactions // Journal of Molecular Catalysis. 1978. Vol. 4. No. 6. pp. 387-399.
GOST all authors (up to 50)
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Varfolomeev S. D., Berezin L. V. Enzymes as catalysts of electrochemical reactions // Journal of Molecular Catalysis. 1978. Vol. 4. No. 6. pp. 387-399.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1016/0304-5102(78)80009-1
UR - https://doi.org/10.1016/0304-5102(78)80009-1
TI - Enzymes as catalysts of electrochemical reactions
T2 - Journal of Molecular Catalysis
AU - Varfolomeev, S. D.
AU - Berezin, L V
PY - 1978
DA - 1978/12/01
PB - Elsevier
SP - 387-399
IS - 6
VL - 4
SN - 1001-3555
SN - 0304-5102
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1978_Varfolomeev,
author = {S. D. Varfolomeev and L V Berezin},
title = {Enzymes as catalysts of electrochemical reactions},
journal = {Journal of Molecular Catalysis},
year = {1978},
volume = {4},
publisher = {Elsevier},
month = {dec},
url = {https://doi.org/10.1016/0304-5102(78)80009-1},
number = {6},
pages = {387--399},
doi = {10.1016/0304-5102(78)80009-1}
}
Cite this
MLA
Copy
Varfolomeev, S. D., and L V Berezin. “Enzymes as catalysts of electrochemical reactions.” Journal of Molecular Catalysis, vol. 4, no. 6, Dec. 1978, pp. 387-399. https://doi.org/10.1016/0304-5102(78)80009-1.