Thermodynamics of the sodium bromide-methanol-water and sodium bromide-ethanol-water two ternary systems by the measurements of electromotive force at 298. 15K
Publication type: Journal Article
Publication date: 1993-02-01
scimago Q2
wos Q2
SJR: 0.578
CiteScore: 5.4
Impact factor: 2.7
ISSN: 03783812, 18790224
Physical and Theoretical Chemistry
General Chemical Engineering
General Physics and Astronomy
Abstract
Electromotive force measurements of the following cells ; are carried out. The molal concentration m of NaBr in methanol-water mixed solvents changes from 0. 01m to 3.0m and those in ethanol—water mixed solvents from 0. 01m to 5.0m. The weight percent of methanol or ethanol in the mixed solvent w equals 0, 10, 20, 40, 60, 80, 90 and 100 respectively. Calculations of standard cell potential of each conditions are made by using the extended Debye—Huckel equation and the Pitzer equation. The calculation results of standard potentials of both of the two equations are in good agreement with each other. The ionic association effect of NaBr in the mixed solvent are investigated by the Pitzer—Simonson equation extended to ion pairing.
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Total citations:
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Han S., Pan H. Thermodynamics of the sodium bromide-methanol-water and sodium bromide-ethanol-water two ternary systems by the measurements of electromotive force at 298. 15K // Fluid Phase Equilibria. 1993. Vol. 83. pp. 261-270.
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Han S., Pan H. Thermodynamics of the sodium bromide-methanol-water and sodium bromide-ethanol-water two ternary systems by the measurements of electromotive force at 298. 15K // Fluid Phase Equilibria. 1993. Vol. 83. pp. 261-270.
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TY - JOUR
DO - 10.1016/0378-3812(93)87029-z
UR - https://doi.org/10.1016/0378-3812(93)87029-z
TI - Thermodynamics of the sodium bromide-methanol-water and sodium bromide-ethanol-water two ternary systems by the measurements of electromotive force at 298. 15K
T2 - Fluid Phase Equilibria
AU - Han, Shijun
AU - Pan, Huanquan
PY - 1993
DA - 1993/02/01
PB - Elsevier
SP - 261-270
VL - 83
SN - 0378-3812
SN - 1879-0224
ER -
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BibTex (up to 50 authors)
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@article{1993_Han,
author = {Shijun Han and Huanquan Pan},
title = {Thermodynamics of the sodium bromide-methanol-water and sodium bromide-ethanol-water two ternary systems by the measurements of electromotive force at 298. 15K},
journal = {Fluid Phase Equilibria},
year = {1993},
volume = {83},
publisher = {Elsevier},
month = {feb},
url = {https://doi.org/10.1016/0378-3812(93)87029-z},
pages = {261--270},
doi = {10.1016/0378-3812(93)87029-z}
}