Study of anisotropic spin dynamics in pristine trans-polyacetylene by means of 2 mm EPR spectroscopy
Publication type: Journal Article
Publication date: 1992-01-01
scimago Q1
wos Q2
SJR: 0.787
CiteScore: 8.3
Impact factor: 4.6
ISSN: 03796779
Materials Chemistry
Metals and Alloys
Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Mechanical Engineering
Mechanics of Materials
Abstract
Spin-lattice and spin-spin relaxation times of paramagnetic centres in initial and partly oriented trans -polyacetylene have been measured by a saturation method at 2 mm waveband EPR in the 90–300 K temperature range. Temperature dependences of the intrachain diffusion and interchain hopping rates of the paramagnetic centres in the latter samples are evaluated. Spin dynamics in the oriented sample has been shown to depend on its orientation in a magnetic field and is in good agreement with Kivelson's theory of charge transport in trans -polyacetylene via intersoliton electron hopping. Temperature evaluation of the neutral soliton width has been investigated.
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Krinichnyi V. et al. Study of anisotropic spin dynamics in pristine trans-polyacetylene by means of 2 mm EPR spectroscopy // Synthetic Metals. 1992. Vol. 46. No. 1. pp. 13-22.
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Krinichnyi V., Pelekh A. E., Tkachenko L. I., Kozub G. Study of anisotropic spin dynamics in pristine trans-polyacetylene by means of 2 mm EPR spectroscopy // Synthetic Metals. 1992. Vol. 46. No. 1. pp. 13-22.
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RIS
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TY - JOUR
DO - 10.1016/0379-6779(92)90315-a
UR - https://doi.org/10.1016/0379-6779(92)90315-a
TI - Study of anisotropic spin dynamics in pristine trans-polyacetylene by means of 2 mm EPR spectroscopy
T2 - Synthetic Metals
AU - Krinichnyi, V.I.
AU - Pelekh, A E
AU - Tkachenko, L I
AU - Kozub, G.I
PY - 1992
DA - 1992/01/01
PB - Elsevier
SP - 13-22
IS - 1
VL - 46
SN - 0379-6779
ER -
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@article{1992_Krinichnyi,
author = {V.I. Krinichnyi and A E Pelekh and L I Tkachenko and G.I Kozub},
title = {Study of anisotropic spin dynamics in pristine trans-polyacetylene by means of 2 mm EPR spectroscopy},
journal = {Synthetic Metals},
year = {1992},
volume = {46},
publisher = {Elsevier},
month = {jan},
url = {https://doi.org/10.1016/0379-6779(92)90315-a},
number = {1},
pages = {13--22},
doi = {10.1016/0379-6779(92)90315-a}
}
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MLA
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Krinichnyi, V.I., et al. “Study of anisotropic spin dynamics in pristine trans-polyacetylene by means of 2 mm EPR spectroscopy.” Synthetic Metals, vol. 46, no. 1, Jan. 1992, pp. 13-22. https://doi.org/10.1016/0379-6779(92)90315-a.