Radiation Physics and Chemistry

, volume 48 , issue 3 , pages 261-269

Radiation-induced degradation of alkane molecules in solid rare gas matrices

Vladimir I. Feldman ¹

F F Sukhov ¹

N A Slovokhotova ¹

V P Bazov ¹

Hide authors affiliations Show authors affiliations: 1 affiliation

L. Ya. Karpov Institute of Physical Chemistry, Vorontsovo Pole Str. 10, Moscow 103064, Russia |

Publication type: Journal Article

Publication date: 1996-09-01

Elsevier

Radiation Physics and Chemistry

scimago Q2

wos Q1

SJR: 0.543

CiteScore: 5.6

Impact factor: 3.3

ISSN: 0969806X, 18790895

DOI: 10.1016/0969-806X(95)00453-5

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Radiation

Abstract

Abstract The radiation-induced degradation of heptane molecules in solid argon and xenon matrices at 15 K was studied using low-temperature IR spectroscopy. The total radiation-chemical yield of the destruction of heptane molecules in argon (mole ratio 500:1) was estimated to be 1.4 molecule per 100 eV. Methane, vinyl- and trans-vinylene-type olefins, and allyl-type radicals were identified among the main radiolysis products in both matrices. The C-C bond rupture is favoured in argon probably due to formation of excited heptane cations in the hole transfer in this matrix. An indication of the radical cation trapping was obtained in a xenon matrix containing an electron scavenger (Freon-113). The mechanism of the radiation-induced degradation of alkane molecules and the fate of the primary cations in rigid inert media are discussed.

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3 citations

Tyurin Daniil

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PhD in Chemistry

69 publications, 680 citations

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Lomonosov Moscow State University

Computational chemistry

Computational methods in chemistry

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IR spectroscopy

Interaction of X-ray and synchrotron radiation with matter

Matrix isolation

Molecular modeling

Molecular spectroscopy

Non-covalent Interactions

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Feldman V. I. et al. Radiation-induced degradation of alkane molecules in solid rare gas matrices // Radiation Physics and Chemistry. 1996. Vol. 48. No. 3. pp. 261-269.

GOST all authors (up to 50) Copy

Feldman V. I., Sukhov F. F., Slovokhotova N. A., Bazov V. P. Radiation-induced degradation of alkane molecules in solid rare gas matrices // Radiation Physics and Chemistry. 1996. Vol. 48. No. 3. pp. 261-269.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1016/0969-806X(95)00453-5

UR - https://linkinghub.elsevier.com/retrieve/pii/0969806X95004535

TI - Radiation-induced degradation of alkane molecules in solid rare gas matrices

T2 - Radiation Physics and Chemistry

AU - Feldman, Vladimir I.

AU - Sukhov, F F

AU - Slovokhotova, N A

AU - Bazov, V P

PY - 1996

DA - 1996/09/01

PB - Elsevier

SP - 261-269

IS - 3

VL - 48

SN - 0969-806X

SN - 1879-0895

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{1996_Feldman,

author = {Vladimir I. Feldman and F F Sukhov and N A Slovokhotova and V P Bazov},

title = {Radiation-induced degradation of alkane molecules in solid rare gas matrices},

journal = {Radiation Physics and Chemistry},

year = {1996},

volume = {48},

publisher = {Elsevier},

month = {sep},

url = {https://linkinghub.elsevier.com/retrieve/pii/0969806X95004535},

number = {3},

pages = {261--269},

doi = {10.1016/0969-806X(95)00453-5}

}

MLA

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MLA Copy

Feldman, Vladimir I., et al. “Radiation-induced degradation of alkane molecules in solid rare gas matrices.” Radiation Physics and Chemistry, vol. 48, no. 3, Sep. 1996, pp. 261-269. https://linkinghub.elsevier.com/retrieve/pii/0969806X95004535.