Radiation-induced degradation of alkane molecules in solid rare gas matrices
Тип публикации: Journal Article
Дата публикации: 1996-09-01
scimago Q2
wos Q1
white level БС1
SJR: 0.536
CiteScore: 5.6
Impact factor: 3.3
ISSN: 0969806X, 18790895
Radiation
Краткое описание
Abstract The radiation-induced degradation of heptane molecules in solid argon and xenon matrices at 15 K was studied using low-temperature IR spectroscopy. The total radiation-chemical yield of the destruction of heptane molecules in argon (mole ratio 500:1) was estimated to be 1.4 molecule per 100 eV. Methane, vinyl- and trans-vinylene-type olefins, and allyl-type radicals were identified among the main radiolysis products in both matrices. The C-C bond rupture is favoured in argon probably due to formation of excited heptane cations in the hole transfer in this matrix. An indication of the radical cation trapping was obtained in a xenon matrix containing an electron scavenger (Freon-113). The mechanism of the radiation-induced degradation of alkane molecules and the fate of the primary cations in rigid inert media are discussed.
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ГОСТ
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Feldman V. I. et al. Radiation-induced degradation of alkane molecules in solid rare gas matrices // Radiation Physics and Chemistry. 1996. Vol. 48. No. 3. pp. 261-269.
ГОСТ со всеми авторами (до 50)
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Feldman V. I., Sukhov F. F., Slovokhotova N. A., Bazov V. P. Radiation-induced degradation of alkane molecules in solid rare gas matrices // Radiation Physics and Chemistry. 1996. Vol. 48. No. 3. pp. 261-269.
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RIS
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TY - JOUR
DO - 10.1016/0969-806X(95)00453-5
UR - https://linkinghub.elsevier.com/retrieve/pii/0969806X95004535
TI - Radiation-induced degradation of alkane molecules in solid rare gas matrices
T2 - Radiation Physics and Chemistry
AU - Feldman, Vladimir I.
AU - Sukhov, F F
AU - Slovokhotova, N A
AU - Bazov, V P
PY - 1996
DA - 1996/09/01
PB - Elsevier
SP - 261-269
IS - 3
VL - 48
SN - 0969-806X
SN - 1879-0895
ER -
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BibTex (до 50 авторов)
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@article{1996_Feldman,
author = {Vladimir I. Feldman and F F Sukhov and N A Slovokhotova and V P Bazov},
title = {Radiation-induced degradation of alkane molecules in solid rare gas matrices},
journal = {Radiation Physics and Chemistry},
year = {1996},
volume = {48},
publisher = {Elsevier},
month = {sep},
url = {https://linkinghub.elsevier.com/retrieve/pii/0969806X95004535},
number = {3},
pages = {261--269},
doi = {10.1016/0969-806X(95)00453-5}
}
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MLA
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Feldman, Vladimir I., et al. “Radiation-induced degradation of alkane molecules in solid rare gas matrices.” Radiation Physics and Chemistry, vol. 48, no. 3, Sep. 1996, pp. 261-269. https://linkinghub.elsevier.com/retrieve/pii/0969806X95004535.
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