Radiation Physics and Chemistry

, том 48 , издание 3 , страницы 261-269

Radiation-induced degradation of alkane molecules in solid rare gas matrices

Тип публикации: Journal Article

Дата публикации: 1996-09-01

Elsevier

Radiation Physics and Chemistry

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SJR: 0.543

CiteScore: 5.6

Impact factor: 3.3

ISSN: 0969806X, 18790895

DOI: 10.1016/0969-806X(95)00453-5

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Radiation

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Abstract The radiation-induced degradation of heptane molecules in solid argon and xenon matrices at 15 K was studied using low-temperature IR spectroscopy. The total radiation-chemical yield of the destruction of heptane molecules in argon (mole ratio 500:1) was estimated to be 1.4 molecule per 100 eV. Methane, vinyl- and trans-vinylene-type olefins, and allyl-type radicals were identified among the main radiolysis products in both matrices. The C-C bond rupture is favoured in argon probably due to formation of excited heptane cations in the hole transfer in this matrix. An indication of the radical cation trapping was obtained in a xenon matrix containing an electron scavenger (Freon-113). The mechanism of the radiation-induced degradation of alkane molecules and the fate of the primary cations in rigid inert media are discussed.

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3 цитирования

Тюрин Даниил

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73 публикации, 692 цитирования

Индекс Хирша: 15

Московский государственный университет имени М.В. Ломоносова

Области научных интересов

Ab initio

Matrix isolation

Астрофизика

Взаимодействие рентгеновского и синхротронного излучений с веществом

Высокопроизводительные вычисления

Вычислительная химия

ИК-спектроскопия

Квантовая химия

Космические исследования

Криогенная техника

Матричная изоляция

Механизмы реакций

Молекулярная спектроскопия

Молекулярное моделирование

Невалентные взаимодействия

Нековалентные взаимодействия

Расчетные методы в химии

Рентгеновское излучение

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Feldman V. I. et al. Radiation-induced degradation of alkane molecules in solid rare gas matrices // Radiation Physics and Chemistry. 1996. Vol. 48. No. 3. pp. 261-269.

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Feldman V. I., Sukhov F. F., Slovokhotova N. A., Bazov V. P. Radiation-induced degradation of alkane molecules in solid rare gas matrices // Radiation Physics and Chemistry. 1996. Vol. 48. No. 3. pp. 261-269.

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TY - JOUR

DO - 10.1016/0969-806X(95)00453-5

UR - https://linkinghub.elsevier.com/retrieve/pii/0969806X95004535

TI - Radiation-induced degradation of alkane molecules in solid rare gas matrices

T2 - Radiation Physics and Chemistry

AU - Feldman, Vladimir I.

AU - Sukhov, F F

AU - Slovokhotova, N A

AU - Bazov, V P

PY - 1996

DA - 1996/09/01

PB - Elsevier

SP - 261-269

IS - 3

VL - 48

SN - 0969-806X

SN - 1879-0895

ER -

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@article{1996_Feldman,

author = {Vladimir I. Feldman and F F Sukhov and N A Slovokhotova and V P Bazov},

title = {Radiation-induced degradation of alkane molecules in solid rare gas matrices},

journal = {Radiation Physics and Chemistry},

year = {1996},

volume = {48},

publisher = {Elsevier},

month = {sep},

url = {https://linkinghub.elsevier.com/retrieve/pii/0969806X95004535},

number = {3},

pages = {261--269},

doi = {10.1016/0969-806X(95)00453-5}

}

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Feldman, Vladimir I., et al. “Radiation-induced degradation of alkane molecules in solid rare gas matrices.” Radiation Physics and Chemistry, vol. 48, no. 3, Sep. 1996, pp. 261-269. https://linkinghub.elsevier.com/retrieve/pii/0969806X95004535.