Radiation Physics and Chemistry, volume 47, issue 4, pages 559-562
Pulse radiolysis study of 5-amino tetrazole in aqueous solutions
Publication type: Journal Article
Publication date: 1996-04-01
Journal:
Radiation Physics and Chemistry
Quartile SCImago
Q2
Quartile WOS
Q1
Impact factor: 2.9
ISSN: 0969806X
Radiation
Abstract
Reactions of e aq − , H-atoms and OH radicals have been studied with 5-amino tetrazole (ATZ) in aqueous solution. e aq − reaction in the pH range 4.5–9 did not give any light absorbing transient species but NH 3 was obtained as a product indicating that the site for e aq − reaction is the −NH 2 group. In the case of OH radical reaction, a transient spectrum with λ max at 340 nm was obtained at pH 7.5. An identical spectrum was produced by the reaction of SO 4 − radicals with ATZ at neutral pH indicating that both OH radical and SO 4 − radical react by one electron oxidation. The rate constants for the reactions of e aq − and OH with ATZ at pH 7.5 were found to be 6 × 10 7 and 5.2 × 10 9 dm 3 mol −1 s −1 respectively, whereas the rate constant for H-atom reaction may be 7 dm 3 mol −1 s −1 .
Top-30
Citations by journals
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1
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Journal of Physical and Chemical Reference Data
1 publication, 50%
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Russian Chemical Reviews
1 publication, 50%
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1
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Citations by publishers
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1
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American Institute of Physics (AIP)
1 publication, 50%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 50%
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1
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Dey G. et al. Pulse radiolysis study of 5-amino tetrazole in aqueous solutions // Radiation Physics and Chemistry. 1996. Vol. 47. No. 4. pp. 559-562.
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Dey G., Naik D. B., Kishore K., Moorthy P. N. Pulse radiolysis study of 5-amino tetrazole in aqueous solutions // Radiation Physics and Chemistry. 1996. Vol. 47. No. 4. pp. 559-562.
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TY - JOUR
DO - 10.1016/0969-806x(95)00108-a
UR - https://doi.org/10.1016/0969-806x(95)00108-a
TI - Pulse radiolysis study of 5-amino tetrazole in aqueous solutions
T2 - Radiation Physics and Chemistry
AU - Dey, G.R.
AU - Naik, D. B.
AU - Kishore, K.
AU - Moorthy, P N
PY - 1996
DA - 1996/04/01 00:00:00
PB - Elsevier
SP - 559-562
IS - 4
VL - 47
SN - 0969-806X
ER -
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@article{1996_Dey,
author = {G.R. Dey and D. B. Naik and K. Kishore and P N Moorthy},
title = {Pulse radiolysis study of 5-amino tetrazole in aqueous solutions},
journal = {Radiation Physics and Chemistry},
year = {1996},
volume = {47},
publisher = {Elsevier},
month = {apr},
url = {https://doi.org/10.1016/0969-806x(95)00108-a},
number = {4},
pages = {559--562},
doi = {10.1016/0969-806x(95)00108-a}
}
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MLA
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Dey, G.R., et al. “Pulse radiolysis study of 5-amino tetrazole in aqueous solutions.” Radiation Physics and Chemistry, vol. 47, no. 4, Apr. 1996, pp. 559-562. https://doi.org/10.1016/0969-806x(95)00108-a.