Applied Catalysis A: General

, volume 357 , issue 1 , pages 18-25

Synthesis of gasoline-range hydrocarbons over Mo/HZSM-5 catalysts

Shetian Liu ¹

Amit Gujar ¹

Peter K. Thomas ¹

Hossein Toghiani ¹

Mark. G. White ¹

Hide authors affiliations Show authors affiliations: 1 affiliation

Dave C. Swalm School of Chemical Engineering, Mississippi State University, Mississippi State, MS 39762, United States |

Publication type: Journal Article

Publication date: 2009-03-01

Elsevier

Applied Catalysis A: General

scimago Q2

wos Q2

SJR: 1.000

CiteScore: 8.6

Impact factor: 4.8

ISSN: 0926860X, 18733875

DOI: 10.1016/j.apcata.2008.12.033

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Catalysis

Process Chemistry and Technology

Abstract

Mo/HZSM-5 has been found active in Fischer–Tropsch synthesis (FTS). The catalysts were evaluated under various reaction conditions with low H2/CO (molar ratio ∼1.0) syngas typical of a synthesis gas derived from biomass gasification. Liquid hydrocarbons formed on the Mo/HZSM-5 were composed mainly of alkyl-substituted aromatics and lower branched and cyclized alkanes. Aliphatic hydrocarbons were detected only in trace amounts. Lower hydrocarbons produced included mainly methane, ethane, propane and iso-butane. Higher alcohols and carboxylic acids (C1–C6) were detected in the water phase liquids from FTS. It is supposed that the formation of hydrocarbons on Mo/zeolite is through bifunctional-zeolite acidity and molybdenum metal catalysis via mixed alcohols as the intermediates. Investigation on the effects of zeolite structure indicated that zeolite Y is also an excellent support for Mo in the FTS.

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GOST |

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GOST Copy

Liu S. et al. Synthesis of gasoline-range hydrocarbons over Mo/HZSM-5 catalysts // Applied Catalysis A: General. 2009. Vol. 357. No. 1. pp. 18-25.

GOST all authors (up to 50) Copy

Liu S., Gujar A., Thomas P. K., Toghiani H., White M. G. Synthesis of gasoline-range hydrocarbons over Mo/HZSM-5 catalysts // Applied Catalysis A: General. 2009. Vol. 357. No. 1. pp. 18-25.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1016/j.apcata.2008.12.033

UR - https://doi.org/10.1016/j.apcata.2008.12.033

TI - Synthesis of gasoline-range hydrocarbons over Mo/HZSM-5 catalysts

T2 - Applied Catalysis A: General

AU - Liu, Shetian

AU - Gujar, Amit

AU - Thomas, Peter K.

AU - Toghiani, Hossein

AU - White, Mark. G.

PY - 2009

DA - 2009/03/01

PB - Elsevier

SP - 18-25

IS - 1

VL - 357

SN - 0926-860X

SN - 1873-3875

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2009_Liu,

author = {Shetian Liu and Amit Gujar and Peter K. Thomas and Hossein Toghiani and Mark. G. White},

title = {Synthesis of gasoline-range hydrocarbons over Mo/HZSM-5 catalysts},

journal = {Applied Catalysis A: General},

year = {2009},

volume = {357},

publisher = {Elsevier},

month = {mar},

url = {https://doi.org/10.1016/j.apcata.2008.12.033},

number = {1},

pages = {18--25},

doi = {10.1016/j.apcata.2008.12.033}

}

MLA

Cite this

MLA Copy

Liu, Shetian, et al. “Synthesis of gasoline-range hydrocarbons over Mo/HZSM-5 catalysts.” Applied Catalysis A: General, vol. 357, no. 1, Mar. 2009, pp. 18-25. https://doi.org/10.1016/j.apcata.2008.12.033.

Publisher

Elsevier

Journal

Applied Catalysis A: General

scimago Q2

wos Q2

SJR

1.000

CiteScore

8.6

Impact factor

4.8

ISSN

0926860X (Print)

18733875 (Electronic)