Applied Catalysis B: Environmental, volume 243, pages 734-740

Persian buttercup-like BiOBrxCl1-x solid solution for photocatalytic overall CO2 reduction to CO and O2

Publication typeJournal Article
Publication date2019-04-01
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor22.1
ISSN09263373, 18733883
Catalysis
Process Chemistry and Technology
General Environmental Science
Abstract
The photocatalytic overall conversion of CO2 with H2O to chemical fuel and oxygen mimicking natural photosynthesis is a huge challenge in photocatalysis. This work shows the achievement of the solar-driven photocatalytic overall CO2 reduction with H2O to CO and O2 over a Persian buttercup-like BiOBrxCl1-x solid solution. A CO generation rate of 15.86 μmol g−1 h−1 with the approximate stoichiometric O2 evolution is yielded on BiOBr0.6Cl0.4 solid solution under simulated solar light irradiation, which was about 7.5 and 10.2 times higher than that of pure BiOCl (2.11 μmol g−1 h−1) and BiOBr (1.55 μmol g−1 h−1), respectively. The enhanced photoactivity is contributed to the mediate band gap and energy level tuned by the formation of BiOBrxCl1-x solid solution to facilitate the separation of photogenerated charges. Besides the unique electron structure, the photoinduced oxygen vacancy (OV) formed on BiOBrxCl1-x solid solution also plays an important role in the CO2 reduction.

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Gao M. et al. Persian buttercup-like BiOBrxCl1-x solid solution for photocatalytic overall CO2 reduction to CO and O2 // Applied Catalysis B: Environmental. 2019. Vol. 243. pp. 734-740.
GOST all authors (up to 50) Copy
Gao M., Yang J., Sun T., Zhang Z., Zhang D., HUANG H., Lin H., Fang Y., Wang X. Persian buttercup-like BiOBrxCl1-x solid solution for photocatalytic overall CO2 reduction to CO and O2 // Applied Catalysis B: Environmental. 2019. Vol. 243. pp. 734-740.
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RIS Copy
TY - JOUR
DO - 10.1016/j.apcatb.2018.11.020
UR - https://doi.org/10.1016/j.apcatb.2018.11.020
TI - Persian buttercup-like BiOBrxCl1-x solid solution for photocatalytic overall CO2 reduction to CO and O2
T2 - Applied Catalysis B: Environmental
AU - Gao, Meichao
AU - Yang, Jinxiang
AU - Sun, Tao
AU - Zhang, Zizhong
AU - Zhang, Dafeng
AU - HUANG, HUIJUAN
AU - Lin, Huaxiang
AU - Fang, Yi
AU - Wang, Xuxu
PY - 2019
DA - 2019/04/01 00:00:00
PB - Elsevier
SP - 734-740
VL - 243
SN - 0926-3373
SN - 1873-3883
ER -
BibTex
Cite this
BibTex Copy
@article{2019_Gao,
author = {Meichao Gao and Jinxiang Yang and Tao Sun and Zizhong Zhang and Dafeng Zhang and HUIJUAN HUANG and Huaxiang Lin and Yi Fang and Xuxu Wang},
title = {Persian buttercup-like BiOBrxCl1-x solid solution for photocatalytic overall CO2 reduction to CO and O2},
journal = {Applied Catalysis B: Environmental},
year = {2019},
volume = {243},
publisher = {Elsevier},
month = {apr},
url = {https://doi.org/10.1016/j.apcatb.2018.11.020},
pages = {734--740},
doi = {10.1016/j.apcatb.2018.11.020}
}
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