Applied Catalysis B: Environmental, volume 297, pages 120474

V2C MXene synergistically coupling FeNi LDH nanosheets for boosting oxygen evolution reaction

Yafeng Chen ^{1, 2}

Heliang Yao ³

Fantao Kong ³

Tian Han ³

Meng Ge ³

Shuize Wang ⁴

Xinping Mao ⁴

Xiangzhi Cui ²

Xinmei Hou ⁴

Jianlin Shi ³

Hide authors affiliations Show authors affiliations: 4 affiliations

Beijing Advanced Innovation Center for Materials Genome Engineering, Collaborative Innovation Center of Steel Technology, University of Science and Technology Beijing, Beijing, 100083, China |

The State Key Laboratory of High Performance Ceramics and Superfine Microstructures, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai, 200050, China |

The State Key Laboratory of High Performance Ceramics and Superfine Microstructures, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China |

⁴

Beijing Advanced Innovation Center for Materials Genome Engineering, Collaborative Innovation Center of Steel Technology, University of Science and Technology Beijing, Beijing 100083, China |

Publication type: Journal Article

Publication date: 2021-11-01

Elsevier

Journal: Applied Catalysis B: Environmental

Quartile SCImago

Quartile WOS

Impact factor: 22.1

ISSN: 09263373, 18733883

DOI: 10.1016/j.apcatb.2021.120474

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Catalysis

Process Chemistry and Technology

General Environmental Science

Abstract

• The charge transfer from LDHs to V 2 C results in the valence states increase of Ni and Fe irons. • The strong interaction between FeNi-LDHs and V 2 C facilitates adsorption/desorption balance in OER. • The as-fabricated rechargeable Zn-air battery reveals superior power density and well durability. Oxygen evolution reaction (OER) is a pivotal electrochemical reaction process for many renewable energy technologies. Due to the sluggish OER kinetics, searching for efficient low-cost non-precious metal catalysts is one of the crucial but very challenging steps. Herein, V 2 C MXene synergistically coupled with hypophosphite-intercalated FeNi (oxy)hydroxide (H 2 PO 2 − /FeNi-LDH-V 2 C) electrocatalyst is synthesized. The H 2 PO 2 − /FeNi-LDH-V 2 C exhibits excellent OER performance with an overpotential of 250 mV (η 10 ) and small Tafel slope of 46.5 mV dec −1 in 1.0 M KOH electrolyte, and excellent rechargeable Zn-air battery performance with superior open circuit potential (1.42 eV), power density (137 mW cm −2 ) and well durability. The strong interaction and electronic coupling with prominent charge-transfer between FeNi-LDHs and V 2 C MXene endow the composite significant OER performance and structural stability, and the adsorption/desorption balance for the OER reaction pathway, eventually promoting the intrinsic activity. This work demonstrates the great promise of MXene-based nanohybrids as advanced electrocatalysts for renewable energy applications.

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Citations by journals

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Journal of Colloid and Interface Science	Journal of Colloid and Interface Science, 11, 8.73% Journal of Colloid and Interface Science 11 publications, 8.73%
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Advanced Functional Materials	Advanced Functional Materials, 3, 2.38% Advanced Functional Materials 3 publications, 2.38%
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ECS Journal of Solid State Science and Technology	ECS Journal of Solid State Science and Technology, 1, 0.79% ECS Journal of Solid State Science and Technology 1 publication, 0.79%
ACS applied materials & interfaces	ACS applied materials & interfaces, 1, 0.79% ACS applied materials & interfaces 1 publication, 0.79%
Frontiers of Physics	Frontiers of Physics, 1, 0.79% Frontiers of Physics 1 publication, 0.79%
Bioresource Technology	Bioresource Technology, 1, 0.79% Bioresource Technology 1 publication, 0.79%
Chinese Journal of Catalysis	Chinese Journal of Catalysis, 1, 0.79% Chinese Journal of Catalysis 1 publication, 0.79%
Science of the Total Environment	Science of the Total Environment, 1, 0.79% Science of the Total Environment 1 publication, 0.79%
Nature Communications	Nature Communications, 1, 0.79% Nature Communications 1 publication, 0.79%
Coordination Chemistry Reviews	Coordination Chemistry Reviews, 1, 0.79% Coordination Chemistry Reviews 1 publication, 0.79%
	2 4 6 8 10 12

Citations by publishers

	10 20 30 40 50 60 70
Elsevier	Elsevier, 66, 52.38% Elsevier 66 publications, 52.38%
Wiley	Wiley, 16, 12.7% Wiley 16 publications, 12.7%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 14, 11.11% Royal Society of Chemistry (RSC) 14 publications, 11.11%
American Chemical Society (ACS)	American Chemical Society (ACS), 9, 7.14% American Chemical Society (ACS) 9 publications, 7.14%
Multidisciplinary Digital Publishing Institute (MDPI)	Multidisciplinary Digital Publishing Institute (MDPI), 7, 5.56% Multidisciplinary Digital Publishing Institute (MDPI) 7 publications, 5.56%
Springer Nature	Springer Nature, 5, 3.97% Springer Nature 5 publications, 3.97%
The Electrochemical Society	The Electrochemical Society, 4, 3.17% The Electrochemical Society 4 publications, 3.17%
IOP Publishing	IOP Publishing, 2, 1.59% IOP Publishing 2 publications, 1.59%
OAE Publishing Inc.	OAE Publishing Inc., 1, 0.79% OAE Publishing Inc. 1 publication, 0.79%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 0.79% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 0.79%
	10 20 30 40 50 60 70

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Chen Y. et al. V2C MXene synergistically coupling FeNi LDH nanosheets for boosting oxygen evolution reaction // Applied Catalysis B: Environmental. 2021. Vol. 297. p. 120474.

GOST all authors (up to 50) Copy

Chen Y., Yao H., Kong F., Han T., Ge M., Wang S., Mao X., Cui X., Hou X., Shi J. V2C MXene synergistically coupling FeNi LDH nanosheets for boosting oxygen evolution reaction // Applied Catalysis B: Environmental. 2021. Vol. 297. p. 120474.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1016/j.apcatb.2021.120474

UR - https://doi.org/10.1016/j.apcatb.2021.120474

TI - V2C MXene synergistically coupling FeNi LDH nanosheets for boosting oxygen evolution reaction

T2 - Applied Catalysis B: Environmental

AU - Chen, Yafeng

AU - Yao, Heliang

AU - Kong, Fantao

AU - Han, Tian

AU - Ge, Meng

AU - Wang, Shuize

AU - Mao, Xinping

AU - Cui, Xiangzhi

AU - Hou, Xinmei

AU - Shi, Jianlin

PY - 2021

DA - 2021/11/01 00:00:00

PB - Elsevier

SP - 120474

VL - 297

SN - 0926-3373

SN - 1873-3883

ER -

BibTex

Cite this

BibTex Copy

@article{2021_Chen,

author = {Yafeng Chen and Heliang Yao and Fantao Kong and Tian Han and Meng Ge and Shuize Wang and Xinping Mao and Xiangzhi Cui and Xinmei Hou and Jianlin Shi},

title = {V2C MXene synergistically coupling FeNi LDH nanosheets for boosting oxygen evolution reaction},

journal = {Applied Catalysis B: Environmental},

year = {2021},

volume = {297},

publisher = {Elsevier},

month = {nov},

url = {https://doi.org/10.1016/j.apcatb.2021.120474},

pages = {120474},

doi = {10.1016/j.apcatb.2021.120474}

}

Found error?

Publisher

Elsevier

Journal

Applied Catalysis B: Environmental

Quartile SCImago

Quartile WOS

Impact factor

22.1

ISSN

09263373 (Print)
18733883 (Electronic)